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硅酸盐通报 ›› 2011, Vol. 30 ›› Issue (6): 1304-1308.

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粉煤灰基多孔陶瓷对孔雀石绿的脱色研究

高如琴;王阳阳;张润涛;王燕;全建军   

  1. 华北水利水电学院,郑州,450011;河南省耕生高温材料有限公司,郑州,450001
  • 出版日期:2011-12-15 发布日期:2021-01-18
  • 基金资助:
    Natural Science Research Project of He' nan Educational Committee and Scientific(2011 B610005)%Research Foundation from North China University of Water Resources and Electric Power(200930)

Study on Decolorization of Fly Ash-based Porous Ceramics for Malachite Green

GAO Ru-qin;WANG Yang-yang;ZHANG Run-tao;WANG Yan;QUAN Jian-jun   

  • Online:2011-12-15 Published:2021-01-18

摘要: 以粉煤灰为主要原料,添加超细电气石粉和烧结助剂,采用湿式超细研磨和低温煅烧工艺,制备粉煤灰基多孔陶瓷.利用扫描电镜、X射线衍射仪等对材料的结构和性能进行了表征.通过紫外-可见分光光度计,分析了粉煤灰基多孔陶瓷对孔雀石绿的脱色效果.结果表明:粉煤灰基多孔陶瓷孔径细小均匀,具有较强的吸附性;适量超细电气石粉的引入使粉煤灰基多孔陶瓷具有一定的降解能力,反应5h,孔雀石绿溶液脱色率达89.3%,结合傅立叶变换红外光谱,探讨了脱色前后孔雀石绿结构的变化,并进一步分析了孔雀石绿的脱色机理.

关键词: 粉煤灰基多孔陶瓷;电气石;孔雀石绿;脱色机理

Abstract: Fly ash-based porous ceramics was prepared by wet ultra-fine grinding and low-temperature calcining process using fly ash as main materials and ultra-fine tourmaline and binding agent as additive.The structure and properties of material were characterized by SEM,XRD,and decolorizing effect of fly ash-based porous ceramics to degrade malachite green (MG) was analyzed by ultraviolet-visible spectrophotometer.The results indicated that the materials had fine-uniform pore size and excellent adsorptivity.The addition of ultra-fine tourmaline proviede fly ash-based porous ceramics with degradation capacity,and the decolorizing rate of malachite green aqueous achieved to 89.3%.By means of FT-IR,the changes of the structure of malachite green were studied before and after decolorizing,and decolorizing mechanism of malachite green was also analyzed.

Key words: fly ash-based porous ceramics;tourmaline;malachite green;decolorizing mechanism

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