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硅酸盐通报 ›› 2009, Vol. 28 ›› Issue (5): 1060-1063.

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(SrZrO_3)_(10)(SrTiO_3)_(90)缓冲层对PZT结晶及性能的影响

辛红;苏未安;王艳阳   

  1. 西安建筑科技大学理学院,西安,710055;江西理工大学理学院,赣州,341000
  • 发布日期:2021-01-15

Effect of (SrZrO_3)_(10)(SrTiO_3)_(90) Buffer Layer on the Crystallization and Ferroelectric Properties of PbZr0.52Ti0.48O3 Thin Films

XIN Hong;SU Wei-an;WANG Yan-yang   

  • Published:2021-01-15

摘要: _采用Sol-gel法制备了PbZr_0.52Ti_0.48O_3 (PZT)薄膜,并研究了(SrZrO_3)_(10)(SrTiO_3)_(90)((SZO)_10(STO)_90)缓冲层对PZT薄膜结晶和性能的影响.X射线衍射(XRD)结果表明:(SZO)_10(STO)_90缓冲层对PZT薄膜结晶有取向诱导作用,由(SZO)_10(STO)_90诱导的PZT薄膜有很强的(111)择优取向,缓冲层将PZT薄膜的取向度α由45.0%提高到了90.1%以上;PZT的(111)择优取向提高了薄膜的电性能,使剩余极化强度Pr从26.8 μC/cm~2增大到38.8 μC/cm~2.

关键词: 缓冲层;薄膜;结晶;(SZO)_10(STO)_90

Abstract: PbZr_0.52Ti_0.48O_3 (PZT) thin films were prepared by a Sol-gel method with (SZO)_(10)(STO)_(90) buffer layer. The effect of (SZO)_(10)(STO)_(90) buffer layer on the crystallization and ferroelectric properties of PZT thin films was investigated. X-ray diffraction patterns show that the crystallization of PZT thin films varies with buffer layer clearly. (SZO)_(10)(STO)_(90) seeding layer almost results in the formation of a single (111)-textured PZT film, and (111)-orientation degree increases from 45.0% to more then 90.1%. At the same time, ferroelectric properties of the PZT thin film are improved by (SZO)_(10)(STO)_(90) seeding layer, remanent polarization increases from 26.8 μC/cm~2 to 38.8 μC/cm~2.

Key words: buffer layer%thin film%crystallization%(SZO)_10(STO)_90

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