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硅酸盐通报 ›› 2009, Vol. 28 ›› Issue (5): 1038-1041.

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阿利特-硫铝酸钡钙水泥抗硫酸盐侵蚀性能的研究

李贵强;芦令超;王守德;陈诚;尹超男   

  1. 济南大学材料科学与工程学院,济南,250022
  • 发布日期:2021-01-15
  • 基金资助:
    国家重点基础研究发展规划(973计划)(2009CB623101)%山东省自然科学基金(Y2008F49)

Sulfate Resistance of Alite-barium Calcium Sulphoaluminate Cement

LI Gui-qiang;LU Ling-chao;WANG Shou-de;CHEN Cheng;YIN Chao-nan   

  • Published:2021-01-15

摘要: 本文研究了石膏掺量对阿利特-硫铝酸钡钙水泥抗硫酸盐侵蚀性能的影响,并与硅酸盐水泥进行了比较;利用XRD,SEM-EDS等测试方法对侵蚀后水泥水化产物的物相组成和形貌进行了分析.研究结果表明:阿利特-硫铝酸钡钙水泥具有良好的抗硫酸盐侵蚀性能.当石膏掺量为5%时,阿利特-硫铝酸钡钙水泥的抗蚀系数达1.31,而硅酸盐水泥的抗蚀系数仅为0.94.石膏对阿利特-硫铝酸钡钙水泥硬化浆体的致密性有较大影响,进而影响水泥的抗硫酸盐侵蚀性能.同时,对阿利特-硫铝酸钡钙水泥的抗侵蚀机理进行了初步分析.

关键词: 阿利特-硫铝酸钡钙水泥;石膏;硫酸盐;抗蚀性

Abstract: Effect of gypsum content on the sulfate resistance of alite-barium calcium sulphoaluminate cement was investigated. Portland cement was taken for comparison. The composition and microstructure of hardened cement pastes were analyzed by X-ray diffraction and scanning electron microscope. The results show that alite-barium calcium sulphoaluminate cement has better ability of sulfate resistance. The coefficient of resistance to sulfate attack with 5% gypsum addition in alite-barium calcium sulphoaluminate is 1.31, while that in Portland cement is only 0.94. Gypsum can affect the tightness of alite-barium calcium sulphoaluminate cement hardened pastes and further influence the ability of resistance to sulfate attack. At the same time, the mechanism of sulfate resistance of alite-barium calcium sulphoaluminate cement was discussed in this paper.

Key words: alite-barium calcium sulphoaluminate cement%gypsum%sulfate%corrosion resistance

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