B4C含量对非等摩尔五元硼化物陶瓷致密化及力学性能的影响

doi:10.16552/j.cnki.issn1001-1625.2025.0521

硅酸盐通报 ›› 2025, Vol. 44 ›› Issue (10): 3805-3813.DOI: 10.16552/j.cnki.issn1001-1625.2025.0521

B₄C含量对非等摩尔五元硼化物陶瓷致密化及力学性能的影响

王坤, 邱帅航, 邹冀, 季伟, 王为民, 傅正义

武汉理工大学材料复合新技术全国重点实验室,武汉 430070

收稿日期:2025-05-24 修订日期:2025-06-05 出版日期:2025-10-15 发布日期:2025-11-03
通信作者: 邹冀,博士,研究员。E-mail:ji.zou@whut.edu.cn
作者简介:王坤(1999—),男,硕士研究生。主要从事高熵陶瓷的研究。E-mail:278861695@qq.com
基金资助:
国家重点研发计划(2021YFB3701400);湖北省自然科学基金项目(杰出青年学者2022CFA042)

Effect of B₄C Content on Densification and Mechanical Properties of Non-Equimolar Quinary Boride Ceramics

WANG Kun, QIU Shuaihang, ZOU Ji, JI Wei, WANG Weimin, FU Zhengyi

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China

Received:2025-05-24 Revised:2025-06-05 Published:2025-10-15 Online:2025-11-03

摘要/Abstract

摘要： 本文以B₄C为烧结助剂,采用无压烧结工艺制备了(Ti_0.1Zr_0.35Hf_0.35Nb_0.1Ta_0.1)B₂复相陶瓷,并考察了添加不同含量B₄C的样品在1 900~2 200 ℃烧结温度下的显微结构和力学性能。结果表明,B₄C的引入可显著促进陶瓷的致密化,在2 100 ℃下,添加2%和5%(质量分数)B₄C的陶瓷样品均接近全致密,在较低烧结温度(2 000~2 100 ℃)下提高了材料的硬度和断裂韧性。2 100 ℃烧结获得的添加5%B₄C的复相陶瓷展现出较好力学性能,硬度达(21.49±1.17) GPa,断裂韧性为(3.12±0.11) MPa·m^1/2。然而,当烧结温度升高至2 200 ℃时,B₄C形成液相,造成材料致密度和力学性能下降。本研究为复杂组元陶瓷组分设计、烧结助剂调控及无压烧结致密化窗口的建立提供参考。

关键词: 二硼化物陶瓷, B₄C, 非等摩尔, 无压烧结, 致密化, 力学性能

Abstract: In this paper, (Ti_0.1Zr_0.35Hf_0.35Nb_0.1Ta_0.1)B₂ composite ceramics were prepared by pressureless sintering process with B₄C as sintering aid. The microstructure and mechanical properties of samples sintered at 1 900~2 200 ℃ with different content of B₄C were investigated. The results show that the introduction of B₄C can significantly promote the densification of ceramics. At 2 100 ℃, ceramic samples with 2 % and 5 % (mass fraction) B₄C achieve near-complete densification, and the hardness and fracture toughness of materials are improved at lower sintering temperatures (2 000~2 100 ℃). The composite ceramics with 5% B₄C addition sintered at 2 100 ℃ show good mechanical properties, with a hardness of (21.49±1.17) GPa and a fracture toughness of (3.12±0.11) MPa·m^1/2. However, when the sintering temperature rises to 2 200 ℃, B₄C forms a liquid phase, resulting in a decrease in densification and mechanical properties of material. This study provides reference for the design of complex component ceramics composition, the regulation of sintering aid and the establishment of pressureless sintering densification window.

Key words: diboride ceramics, B₄C, non-equimolar, pressureless sintering, densification, mechanical property

中图分类号:

TQ174

王坤, 邱帅航, 邹冀, 季伟, 王为民, 傅正义. B₄C含量对非等摩尔五元硼化物陶瓷致密化及力学性能的影响[J]. 硅酸盐通报, 2025, 44(10): 3805-3813.

WANG Kun, QIU Shuaihang, ZOU Ji, JI Wei, WANG Weimin, FU Zhengyi. Effect of B₄C Content on Densification and Mechanical Properties of Non-Equimolar Quinary Boride Ceramics[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(10): 3805-3813.

参考文献

[1] LIU C, YANG Y, ZHOU Z, et al. (Ti_0.2V_0.2Cr_0.2Nb_0.2Ta_0.2)₂AlC-(Ti_0.2V_0.2Cr_0.2Nb_0.2Ta_0.2)C high-entropy ceramics with low thermal conductivity[J]. Journal of the American Ceramic Society, 2022, 105(4): 2764-2771.
[2] DING Y H, LIU L, GUO R Z, et al. (Hf_0.25Zr_0.25Sn_0.25Ti_0.25)O₂ high-entropy ceramics and their microwave dielectric characteristics[J]. Journal of the American Ceramic Society, 2022, 105(11): 6710-6717.
[3] MA M D, YE B L, HAN Y J, et al. High-pressure sintering of ultrafine-grained high-entropy diboride ceramics[J]. Journal of the American Ceramic Society, 2020, 103(12): 6655-6658.
[4] FILIPOVIC S, OBRADOVIC N, HILMAS G E, et al. A super-hard high entropy boride containing Hf, Mo, Ti, V, and W[J]. Journal of the American Ceramic Society, 2024, 107(7): 4430-4435.
[5] SMITH S M, FAHRENHOLTZ W G, HILMAS G E, et al. Pressureless sintering of dual-phase, high-entropy boride-carbide ceramics[J]. Journal of the American Ceramic Society, 2023, 106(6): 3359-3363.
[6] SMITH S M, FENG L, FAHRENHOLTZ W G, et al. High-entropy boride-carbide ceramics by sequential boro/carbothermal synthesis[J]. Journal of the American Ceramic Society, 2022, 105(9): 5543-5547.
[7] HUO S J, CHEN L, LIU X R, et al. Reactive sintering of dual-phase high-entropy ceramics with superior mechanical properties[J]. Journal of Materials Science & Technology, 2022, 129: 223-227.
[8] LIU J X, SHEN X Q, WU Y, et al. Mechanical properties of hot-pressed high-entropy diboride-based ceramics[J]. Journal of Advanced Ceramics, 2020, 9(4): 503-510.
[9] FENG L, FAHRENHOLTZ W G, HILMAS G E. Processing of dense high-entropy boride ceramics[J]. Journal of the European Ceramic Society, 2020, 40(12): 3815-3823.
[10] BAYRAK K G, UMUTLU Ö N, KOROGLU L, et al. Mechanical characteristics of dual-phase medium-entropy boride/carbide ceramics synthesized through SPS[J]. Journal of the American Ceramic Society, 2025, 108(3): e20282.
[11] WANG F W, XU L, ZOU J, et al. Pressureless densification and properties of high-entropy boride ceramics with B₄C additions[J]. Journal of Materials Science & Technology, 2024, 190: 1-9.
[12] ZOU Q, GU H T, LI Y G, et al. Characterization and analysis of high-entropy boride ceramics sintered at low temperature[J]. Journal of the American Ceramic Society, 2023, 106(5): 2764-2772.
[13] SMITH S M, FAHRENHOLTZ W G, HILMAS G E. Pressureless sintering of high-entropy boride ceramics[J]. Journal of the European Ceramic Society, 2023, 43(12): 5168-5173.
[14] ZHU D, ZHOU J, HUO T, et al. Fabrication of high transmittance AlON ceramics by three-step pressureless sintering[J]. Journal of Materials Research and Technology, 2024, 33: 8992-9000.
[15] MARTIN H P, FENG B, MICHAELIS A. Pressureless sintering and properties of boron carbide composite materials[J]. International Journal of Applied Ceramic Technology, 2020, 17(2): 407-412.
[16] LIU J, YANG Q Q, ZOU J, et al. Strong high-entropy diboride ceramics with oxide impurities at 1 800 ℃[J]. Science China Materials, 2023, 66(5): 2061-2070.
[17] ZHANG Y, GUO W M, JIANG Z B, et al. Dense high-entropy boride ceramics with ultra-high hardness[J]. Scripta Materialia, 2019, 164: 135-139.
[18] QIN M D, GILD J, HU C Z, et al. Dual-phase high-entropy ultra-high temperature ceramics[J]. Journal of the European Ceramic Society, 2020, 40(15): 5037-5050.
[19] GROSS T M, LIU H S, ZHAI Y, et al. The impact of densification on indentation fracture toughness measurements[J]. Journal of the American Ceramic Society, 2020, 103(7): 3920-3929.
[20] SHEN X Q, LIU J X, LI F, et al. Preparation and characterization of diboride-based high entropy (Ti_0.2Zr_0.2Hf_0.2Nb_0.2Ta_0.2)B₂-SiC particulate composites[J]. Ceramics International, 2019, 45(18): 24508-24514.

B₄C含量对非等摩尔五元硼化物陶瓷致密化及力学性能的影响

Effect of B₄C Content on Densification and Mechanical Properties of Non-Equimolar Quinary Boride Ceramics

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	张争奇, 刘祉鑫, 芮照诚, 石杰荣, 杨新红. 地聚物稳定建筑固废再生集料性能研究[J]. 硅酸盐通报, 2025, 44(9): 3347-3354.
[2]	王倩倩, 戴航, 王立川, 张春瑜, 李利平, 王海彦, 张京京. 高氯盐加速侵蚀下水泥-水玻璃双液浆结石体耐久性研究[J]. 硅酸盐通报, 2025, 44(9): 3137-3146.
[3]	义启贵, 湛缕金, 刘祥, 许瑞天, 梁莹, 陈宗平. 碳酸氢钠溶液碳化:一种提高再生骨料混凝土性能的新方法[J]. 硅酸盐通报, 2025, 44(9): 3227-3237.
[4]	朱子龙, 陈培冲, 廖洁, 杨旋, 赵德强, 曲良辰, 王桂明, 沈卫国. 砂砾岩机制砂粒形对混凝土性能的影响[J]. 硅酸盐通报, 2025, 44(9): 3168-3177.
[5]	刘佳钰, 高誉, 刘泽, 温帅云, 王栋民, 危鹏, 张春辉, 朱正江, 李清亚. 水泥固化飞灰-水泥复合胶凝材料的性能与微观结构研究[J]. 硅酸盐通报, 2025, 44(9): 3272-3279.
[6]	张小龙, 王伟, 姚爱军, 王朝晖, 冯希浩, 王杰. 低温低压养护条件下复合胶凝材料性能研究[J]. 硅酸盐通报, 2025, 44(9): 3295-3304.
[7]	余洁歆, 朱艺婷, 庄旭, 陈玉霜, 张广达, 许莉. 以尾矿砂为骨料的绿色工程水泥基复合材料力学性能研究[J]. 硅酸盐通报, 2025, 44(9): 3337-3346.
[8]	黄友奇, 史刘彤, 高玉波, 周林. 蓝宝石单晶的动态力学性能及本构关系研究[J]. 硅酸盐通报, 2025, 44(9): 3391-3401.
[9]	田哲泉, 刘涛, 余刘成, 黄习习, 张艳, 衣向阳. 硫酸盐侵蚀-干湿循环下纤维-水泥改良渣土的力学性能[J]. 硅酸盐通报, 2025, 44(9): 3483-3492.
[10]	阮佳豪, 张雷, 李宇佳. 烧结制度对陶瓷结合剂金刚石砂轮性能的影响[J]. 硅酸盐通报, 2025, 44(8): 2988-2995.
[11]	朱建平, 曹佳楠, 王祚麟, 李根深, 刘松辉, 郑波, 冯春花. 低钙高镁石灰石制备固碳熟料及其碳酸化硬化机理[J]. 硅酸盐通报, 2025, 44(8): 2762-2770.
[12]	白敏, 龙勇, 黄旺明, 胡雄伟, 郭蒙. 匹配养护下氧化镁膨胀剂对砂浆性能和微观结构的影响[J]. 硅酸盐通报, 2025, 44(8): 2781-2789.
[13]	王嘉伟, 李传海, 张冲, 张秀芝. LDHs对超硫酸盐水泥抗碳化性能的影响[J]. 硅酸盐通报, 2025, 44(8): 2790-2800.
[14]	李义胜, 吕伟, 吴赤球, 余正康, 何静, 水中和. 高掺量磷石膏胶凝材料硬化体制备及其性能调节[J]. 硅酸盐通报, 2025, 44(8): 2944-2954.
[15]	王雨铮, 周浩天, 谢鑫, 高旭, 高奎, 曹鸿猷. 车桥耦合振动对拼宽混凝土匀质性的影响[J]. 硅酸盐通报, 2025, 44(8): 2849-2855.