简易水热法制备磁性Fe3O4纳米颗粒及其磁性能研究

doi:10.16552/j.cnki.issn1001-1625.2024.1191

摘要/Abstract

摘要： 磁性四氧化三铁(Fe₃O₄)纳米材料具有高磁响应速率、超顺磁性和生物相容性等优良特性。通过对Fe₃O₄纳米材料的微观形貌进行调控,可以根据储能、催化、医药等实际应用需要,实现对其物理化学性能的有效控制。本文采用简易水热法,通过改变前驱体中Fe³⁺和Fe²⁺的比例、反应温度和反应时间等条件,在未添加形貌调控剂的情况下,制备出了粒径在10~25 nm的球形磁性Fe₃O₄纳米颗粒,最佳制备条件下材料的饱和磁化强度为73.3 emu·g^-1。结果表明,磁性Fe₃O₄纳米颗粒的磁性能与制备条件有着明显的关系,随着水热温度和时间增加,磁性纳米颗粒的粒径及饱和磁化强度先增加再减小。粒径越小,颗粒内部有效磁体积越小,因此饱和磁化强度越低。

关键词: 磁性四氧化三铁, 水热法, 磁性能, 饱和磁化强度, 矫顽力, 超顺磁性

Abstract: Magnetic Fe₃O₄ nanomaterials have excellent magnetic properties including high magnetic response, superparamagnetism and biocompatibility. By regulating the microscopic morphology of the materials, it is possible to achieve effectively control of its physical and chemical properties, such as energy storage, catalysis and medicine, in accordance with the requirements of practical applications. In this paper, according to modify the conditions including the ratio of Fe³⁺ and Fe²⁺ in the precursor, reaction temperature and reaction time, spherical magnetic Fe₃O₄ nanoparticles with particle sizes ranging from 10 to 25 nm were synthesized by a facile hydrothermal method without the addition of a morphology modifier. And the saturation magnetization intensity of the material under the optimum conditions was 73.3 emu·g^-1. The results show that the magnetic properties of Fe₃O₄ nanoparticles have a clear relationship with the preparation conditions. With the increase of hydrothermal temperature and time, the particle size and saturation magnetization intensity of magnetic nanoparticles increase first and then decrease. The smaller the particle size is, the smaller the internal magnetic effective volume is, and therefore the lower the saturation magnetization intensity is.

Key words: magnetic Fe₃O₄, hydrothermal method, magnetic property, saturation magnetization intensity, coercivity, superparamagnetism

中图分类号:

O614.81⁺1

丁界雄, 柳馨, 铁生年, 铁健, 蒋自鹏, 王雅慧, 王培义, 汪清海. 简易水热法制备磁性Fe₃O₄纳米颗粒及其磁性能研究[J]. 硅酸盐通报, 2025, 44(5): 1899-1910.

DING Jiexiong, LIU Xin, TIE Shengnian, TIE Jian, JIANG Zipeng, WANG Yahui, WANG Peiyi, WANG Qinghai. Preparation and Magnetic Performance of Magnetic Fe₃O₄ Nanoparticles by Facile Hydrothermal Method[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(5): 1899-1910.

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简易水热法制备磁性Fe₃O₄纳米颗粒及其磁性能研究

Preparation and Magnetic Performance of Magnetic Fe₃O₄ Nanoparticles by Facile Hydrothermal Method

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