含砷钠钙玻璃对高铝硅酸盐玻璃结构及澄清性能的影响

doi:10.16552/j.cnki.issn1001-1625.2024.0998

硅酸盐通报 ›› 2025, Vol. 44 ›› Issue (2): 717-725.DOI: 10.16552/j.cnki.issn1001-1625.2024.0998

含砷钠钙玻璃对高铝硅酸盐玻璃结构及澄清性能的影响

韩会敏^1,2, 施王明^1,2, 丁梦钊^1,2, 石世岩^1,2, 苏祺^1,2, 罗理达^1,2,3

1.东华大学材料科学与工程学院,纤维材料改性国家重点实验室,上海 201620;
2.东华大学材料科学与工程学院,先进玻璃制造技术教育部工程研究中心,上海 201620;
3.东华大学功能材料研究中心,上海 201620

收稿日期:2024-08-28 修订日期:2024-11-10 出版日期:2025-02-15 发布日期:2025-02-28
通信作者: 罗理达,博士,高级工程师。E-mail:lld@dhu.edu.cn
作者简介:韩会敏(1999—),女,硕士研究生。主要从事硅酸盐玻璃材料的研究。E-mail:1040686450@qq.com
基金资助:
国家重点研发计划(2021YFB3701600)

Effect of Arsenic-Containing Soda-Lime Glass on Structure and Clarification Properties of High-Alumina Silicate Glass

HAN Huimin^1,2, SHI Wangming^1,2, DING Mengzhao^1,2, SHI Shiyan^1,2, SU Qi^1,2, LUO Lida^1,2,3

1. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China;
2. Engineering Research Center of Advanced Glass Manufacturing Technology, Ministry of Education, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China;
3. Institute of Functional Materials, Donghua University, Shanghai 201620, China

Received:2024-08-28 Revised:2024-11-10 Published:2025-02-15 Online:2025-02-28

摘要/Abstract

摘要： 高铝硅酸盐玻璃因具有优异的机械、光学和化学钢化性能而备受关注,但高熔化温度会导致玻璃内气泡和条纹难以消除,这限制了高品质玻璃的制备。As₂O₃是一种低价、高效的玻璃澄清剂,但受安全因素影响已被禁用。本文选取先前研究中制备的已固化12%(质量分数)As₂O₃的钠钙玻璃作为澄清剂,利用红外光谱和拉曼光谱分析了含砷钠钙玻璃的引入对高铝硅酸盐玻璃网络结构的影响。此外,采用超景深显微镜,研究了不同As₂O₃引入量(0%~0.5%,质量分数)对高铝硅酸盐玻璃澄清效果的影响。结果表明,随着含砷钠钙玻璃添加量的增加,高铝硅酸盐玻璃网络结构的聚合度降低。此外,随着As₂O₃引入量的增加,高铝硅酸盐玻璃中气泡缺陷显著减少;As₂O₃引入量为0.5%时,澄清效果最佳,气泡熔占比低至0.14%。

关键词: 高铝硅酸盐玻璃, 含砷钠钙玻璃, 澄清剂, 玻璃结构, 红外光谱, 拉曼光谱, 气泡熔占比

Abstract: High-alumina silicate glasses are of interest because of excellent mechanical, optical, and chemical tempering properties, but high melting temperatures can lead to difficulties in removing bubbles and streaks within the glass, which limits the preparation of high-quality glasses. As₂O₃ is a low-cost and efficient glass clarifier, but As₂O₃ has been banned due to safety factors. In this paper, sodium calcium glass prepared in a previous study that had solidified 12% (mass fraction) As₂O₃ was selected as a clarifier, and the effect of the introduction of arsenic-containing soda-lime glass on the network structure of high-alumina silicate glass was analyzed by FTIR spectra and Raman spectra. In addition, the effects of different As₂O₃ introduction amounts (0% to 0.5%, mass fraction) on the clarification effect of high-alumina silicate glass were investigated by using super depth-of-field microscopy. The results show that the polymerization of the network structure of high-alumina silicate glass decreases with the increase of the addition of arsenic-containing soda-lime glass. In addition, with the increase of As₂O₃ introduction amount, the bubble defects in high-alumina silicate glass are significantly reduced. When As₂O₃ introduction amount is 0.5%, the clarification effect is the best, and the bubble fusion ratio is as low as 0.14%.

Key words: high-alumina silicate glass, arsenic-containing soda-lime glass, clarifier, glass structure, infrared spectrum, Raman spectroscopy, bubble fusion ratio

中图分类号:

TQ171

韩会敏, 施王明, 丁梦钊, 石世岩, 苏祺, 罗理达. 含砷钠钙玻璃对高铝硅酸盐玻璃结构及澄清性能的影响[J]. 硅酸盐通报, 2025, 44(2): 717-725.

HAN Huimin, SHI Wangming, DING Mengzhao, SHI Shiyan, SU Qi, LUO Lida. Effect of Arsenic-Containing Soda-Lime Glass on Structure and Clarification Properties of High-Alumina Silicate Glass[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(2): 717-725.

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含砷钠钙玻璃对高铝硅酸盐玻璃结构及澄清性能的影响

Effect of Arsenic-Containing Soda-Lime Glass on Structure and Clarification Properties of High-Alumina Silicate Glass

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