Preparation and Energy Storage Properties of  CaBi4Ti4O15-Bi(Fe0.93Mn0.05Ti0.02)O3 Ferroelectric Solid Solution Thin Films

Abstract

Abstract: (1-x)CaBi₄Ti₄O₁₅-xBi(Fe_0.93Mn_0.05Ti_0.02)O₃(CBT-xBFMT, x=0, 0.05, 0.10, 0.15) solid solution films were successfully prepared on Pt(111)/TiO₂/SiO₂/Si substrates using metal organic decomposition combined with spin coating technology. And the energy storage properties of CBT thin films were systematically studied by X-ray diffractometer, field emission scanning electron microscope, ferroelectric analyzer and impedance analyzer. The results show that the prepared films all exhibit a polycrystalline bismuth layered structure without other phase formation. The addition of BFMT into thin film obviously enhances the maximum polarization strength P_m and breakdown field strength E_b, reduces the leakage current density. With the increase of BFMT solid solution, the breakdown field strength E_b of CBT-xBFMT film increases first and then decreases, and reaches the maximum value at x=0.10. The maximum polarization strength P_m gradually increases, and the largest polarization strength difference is obtained at x=0.10. The largest polarization intensity difference and breakdown field strength make CBT-0.10BFMT film has the best energy storage properties. The recoverable energy storage density W_rec and energy storage efficiency η of CBT-0.10BFMT film are up to 82.8 J/cm³ and 78.3%, respectively. And its energy storage characteristic has good temperature stability in the temperature range of 25~150 ℃. Therefore, CBT-0.10BFMT ferroelectric film is expected to be used in environmentally friendly micro energy storage devices.

Key words: CaBi₄Ti₄O₁₅ thin film, solid solution, dielectric energy storage, electric breakdown field, polarization intensity difference, high temperature

CLC Number:

TN384

YU Zhiyao, WANG Wenwen, SI Jingxiang, YUAN Xiufang, LI Chenglong, LIN Xiujuan, YANG Changhong. Preparation and Energy Storage Properties of CaBi₄Ti₄O₁₅-Bi(Fe_0.93Mn_0.05Ti_0.02)O₃ Ferroelectric Solid Solution Thin Films[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(6): 2301-2309.

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Preparation and Energy Storage Properties of CaBi₄Ti₄O₁₅-Bi(Fe_0.93Mn_0.05Ti_0.02)O₃ Ferroelectric Solid Solution Thin Films

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