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BULLETIN OF THE CHINESE CERAMIC SOCIETY ›› 2024, Vol. 43 ›› Issue (5): 1663-1672.

• Special Issue on 3D Printing Technology for Inorganic Non-Metallic Materials (II) • Previous Articles     Next Articles

3D Printing Performance of Metakaolin Modified Light Burnt Magnesia-Based Magnesium Phosphate Cement

LI Nan1,2, ZHONG Jianjun1,2, DENG Yongjie1,2, LIANG Yun1,2, WAN Detian3, LI Weihong1,2,4, LI Dongwei1,2   

  1. 1. Key Laboratory for Prediction & Control on Complicated Structure System of the Education Department of Liaoning Province, Dalian University, Dalian 116622, China;
    2. School of Architectural Engineering, Dalian University, Dalian 116622, China;
    3. China Building Materials Academy Co., Ltd., Beijing 100024, China;
    4. Dalian Xueqing Mingfeng CNC Technology Co., Ltd., Dalian 116622, China
  • Received:2023-12-14 Revised:2024-02-04 Online:2024-05-15 Published:2024-06-06

Abstract: In this paper, the 3D printing light burned magnesia-based magnesium phosphate cement material was realized by using the self-developed integrated building 3D printing equipment with mixed stirring and extrusion function. The effect of different metakaolin (MK) content on the properties of 3D printing light burned magnesia-based magnesium phosphate cement was investigated, and combined with XRD and SEM test to further analyze the influence of MK content on the hydration products and crystal appearance of light burnt magnesia-based magnesium phosphate cement. The results show that the setting time and mechanical properties of 3D printing light burnt magnesia-based magnesium phosphate cement increase first and then decrease with the increase of MK content. When MK replaces 4% to 6% of the total mass of magnesia and potassium dihydrogen phosphate, the addition of MK effectively improves the printing performance of light burnt magnesia-based magnesium phosphate cement paste. At this time, the light burned magnesia-based magnesium phosphate cement has good extrusion performance, construction performance and mechanical properties, which can meet the application requirements of 3D printing. The addition of MK does not change the crystal composition of the hydration products of light burnt magnesia-based magnesium phosphate cement, but produces a large number of amorphous amorphous hydration products, which can further fill the gap between hydration products and particles and improve the compactness of structure.

Key words: light burned magnesia, metakaolin, magnesium phosphate cement, 3D printing, printing performance, mechanical property

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