Preparation and Dielectric Properties of CaO-B2O3-SiO2 Glass-Ceramics

Abstract

Abstract: Glass-ceramics with low dielectric constant and low dielectric loss is an important material for the manufacture of low temperature cofired ceramic substrates. CaO-B₂O₃-SiO₂ (CBS) glass-ceramics was prepared by melt-water quenching method, and the effects of m(CaO)/m(SiO₂) mass ratio and B₂O₃ content on the dielectric properties of CBS glass-ceramics were studied. The results show that the main crystalline phases of CBS glass-ceramics are Ca₃Si₃O₉, Ca₂B₂O₅, CaB₂O₄, SiO₂ and Ca₂SiO₄. The dielectric constant increases, the dielectric loss decreases first and then increases with the increase of m(CaO)/m(SiO₂) mass ratio. The increase of wollastonite phase decreases the dielectric loss from 2.87×10^-3 to 1.36×10^-3.The dielectric loss increases with the increase of SiO₂, Ca₂B₂O₅ and CaB₂O₄ content. With the increase of B₂O₃ content, the dielectric constant increases first and then decreases, and the dielectric loss is reversed. When m(CaO)/m(SiO₂) mass ratio is 0.89 and B₂O₃ content is 15%(mass fraction), the coefficient of thermal expansion is 7.16×10^-6 ℃^-1, the dielectric constant is 5.85, and the dielectric loss is 1.37×10^-3 (10 GHz) after sintering at 900 ℃ for 3 h.

Key words: CaO-B₂O₃-SiO₂, glass-ceramics, dielectric constant, dielectric loss, microstructure, low temperature co-firing

CLC Number:

TQ174.1

WEI Zhiyang, WANG Xiaodong, SU Teng, CHEN Huanle, GAO Feng, MIAO Yang. Preparation and Dielectric Properties of CaO-B₂O₃-SiO₂ Glass-Ceramics[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(4): 1274-1283.

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Preparation and Dielectric Properties of CaO-B₂O₃-SiO₂ Glass-Ceramics

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