Synergistic Catalytic Fenton-Like Reaction by Mesoporous CuCo/FeCeOx Catalyst

Abstract

Abstract: The Fenton-like reaction is one of the most effective methods for decomposing organic pollutants in water. Designing efficient heterogeneous catalysts is crucial in this industry. The hard template method was used to construct FeCeO_x materials with Fe-doped ordered mesoporous structures, and the impregnation method was employed to create multi-metallic active sites after loading Cu and Co as the carrier. Methylene blue could be entirely eliminated in 45 min by using an as-prepared catalyst with strong recycling capacity. After 5 runs, methylene blue degradation could still reach 93.3%. The porous structure of the catalyst is conducive to enhancing methylene blue absorption, exposing more active spots, and the synergistic effects of multi-metals promote electron transport, thus boosting the activation efficiency of H₂O₂ and the formation of ·OH.

Key words: fenton-like reaction, mesoporous structure, catalyst, synergistic effect, heterogeneous catalysis

CLC Number:

TQ426.82

CHEN Mengmeng, SONG Yakun, CUI Jiale, CAO Junying, LI Bing, LIU Junhui, LIU Zhen. Synergistic Catalytic Fenton-Like Reaction by Mesoporous CuCo/FeCeO_x Catalyst[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(8): 2985-2993.

References

[1] DIAS E M, PETIT C. Towards the use of metal-organic frameworks for water reuse: a review of the recent advances in the field of organic pollutants removal and degradation and the next steps in the field[J]. Journal of Materials Chemistry A, 2015, 3(45): 22484-22506.
[2] 王建芳, 王君, 杨和平, 等. Fe₃O₄/δ-MnO₂纳米片的制备及其对亚甲基蓝的吸附研究[J]. 无机盐工业, 2019, 51(10): 93-96.
WANG J F, WANG J, YANG H P, et al. Preparation of Fe₃O₄/δ-MnO₂ nanosheet and its adsorption property of methylene blue[J]. Inorganic Chemicals Industry, 2019, 51(10): 93-96 (in Chinese).
[3] PASTRANA-MARTÍNEZ L M, PEREIRA N, RUI L M, et al. Degradation of diphenhydramine by photo-Fenton using magnetically recoverable iron oxide nanoparticles as catalyst[J]. Chemical Engineering Journal, 2015, 261: 45-52.
[4] 宋瑾, 吴凤龙, 王岳俊. 不同负载方式Fe/改性MCM-41催化剂的制备及其降解亚甲基蓝性能研究[J]. 无机盐工业, 2021, 53(11): 122-128.
SONG J, WU F L, WANG Y J. Study on preparation of Fe/modified MCM-41 catalyst with different loading methods and degradation of methylene blue[J]. Inorganic Chemicals Industry, 2021, 53(11): 122-128 (in Chinese).
[5] SUN Y, YANG Z X, TIAN P F, et al. Oxidative degradation of nitrobenzene by a fenton-like reaction with Fe-Cu bimetallic catalysts[J]. Applied Catalysis B: Environmental, 2019, 244: 1-10.
[6] LI J Y, PHAM A N, DAI R B, et al. Recent advances in Cu-Fenton systems for the treatment of industrial wastewaters: role of Cu complexes and Cu composites[J]. Journal of Hazardous Materials, 2020, 392: 122261.
[7] 许乃才, 史丹丹. 不同晶型纳米二氧化锰制备及对亚甲基蓝吸附性能[J]. 无机盐工业, 2021, 53(3): 44-47.
XU N C, SHI D D. Preparation of manganese dioxide nanomaterials with different crystalline and their adsorption properties to methylene blue[J]. Inorganic Chemicals Industry, 2021, 53(3): 44-47 (in Chinese).
[8] GUO X X, HU B, WANG K, et al. Cu embedded Co oxides and its fenton-like activity for metronidazole degradation over a wide pH range: active sites of Cu doped Co₃O₄ with {1 1 2} exposed facet[J]. Chemical Engineering Journal, 2022, 435: 132910.
[9] 赵永琴. Fe₃O₄复合材料的制备及其催化类-Fenton反应性能研究[D]. 大连: 大连理工大学, 2017.
ZHAO Y Q. Preparation of magnetite composites and their Fenton-like catalytic performance[D]. Dalian: Dalian University of Technology, 2017 (in Chinese).
[10] 杨权成, 张开永, 郭德, 等. 介孔硅酸钙吸附亚甲基蓝性能研究[J]. 无机盐工业, 2021, 53(10): 86-91.
YANG Q C, ZHANG K Y, GUO D, et al. Research on adsorption properties of methylene blue by mesoporous calcium silicate[J]. Inorganic Chemicals Industry, 2021, 53(10): 86-91 (in Chinese).
[11] MONTINI T, MELCHIONNA M, MONAI M, et al. Fundamentals and catalytic applications of CeO₂-based materials[J]. Chemical Reviews, 2016, 116(10): 5987-6041.
[12] GOGOI A, NAVGIRE M, SARMA K C, et al. Fe₃O₄-CeO₂ metal oxide nanocomposite as a Fenton-like heterogeneous catalyst for degradation of catechol[J]. Chemical Engineering Journal, 2017, 311: 153-162.
[13] NIU L J, WEI T, LI Q G, et al. Ce-based catalysts used in advanced oxidation processes for organic wastewater treatment: a review[J]. Journal of Environmental Sciences, 2020, 96: 109-116.
[14] 吴春笃, 陈婷婷, 陈闪闪, 等. 类Fenton催化剂氢氧化钴制备及其降解甲基橙的研究[J]. 印染助剂, 2022, 39(9): 29-32+45.
WU C D, CHEN T T, CHEN S S, et al. Preparation of Fenton-like catalyst cobalt hydroxide and its degradation of methyl orange[J]. Textile Auxiliaries, 2022, 39(9): 29-32+45 (in Chinese).
[15] AN K, ALAYOGLU S, MUSSELWHITE N, et al. Enhanced CO oxidation rates at the interface of mesoporous oxides and Pt nanoparticles[J]. Journal of the American Chemical Society, 2013, 135(44): 16689-16696.
[16] KLEITZ F, CHOI S H, RYOO R. Cubic Ia3d large mesoporous silica: synthesis and replication to platinum nanowires, carbon nanorods and carbon nanotubes[J]. Chemical Communications, 2003(17): 2136-2137.
[17] ZHA S X, CHENG Y, GAO Y, et al. Nanoscale zero-valent iron as a catalyst for heterogeneous Fenton oxidation of amoxicillin[J]. Chemical Engineering Journal, 2014, 255: 141-148.
[18] CHO J M, LEE S R, SUN J, et al. Highly ordered mesoporous Fe₂O₃-ZrO₂ bimetal oxides for an enhanced CO hydrogenation activity to hydrocarbons with their structural stability[J]. ACS Catalysis, 2017, 7(9): 5955-5964.
[19] GONG J L, YUE H R, ZHAO Y J, et al. Synthesis of ethanol via syngas on Cu/SiO₂ catalysts with balanced Cu⁰-Cu⁺ sites[J]. Journal of the American Chemical Society, 2012, 134(34): 13922-13925.
[20] LIU J H, ZHANG Z A, LIU B B, et al. Enhanced catalytic performance of Fenton-like reaction: dependence on meso-structure and Cu-Ce interaction[J]. Catalysis Letters, 2022, 152(10): 2947-2955.
[21] DOU R Y, CHENG H, MA J F, et al. Manganese doped magnetic cobalt ferrite nanoparticles for dye degradation via a novel heterogeneous chemical catalysis[J]. Materials Chemistry and Physics, 2020, 240: 122181.

Synergistic Catalytic Fenton-Like Reaction by Mesoporous CuCo/FeCeO_x Catalyst

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	WANG Xin, ZHANG Jinshan, WANG Lan. Research Progress on SCR DeNO_x Metallic Oxide Catalysts [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(2): 509-519.
[2]	LI Yongchun, WANG Yali, WANG Jianfeng, CUI Suping, HUANG Bingyin, WU Xinjiang. Development and Research Status of Coal Combustion Catalyst [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(2): 531-540.
[3]	HU Wenjing, BAN Jinjin, XIE Shunli, WANG Ruizhi, XIAO Jianjun, LEI Honghong. Design and Synthesis of Manganese Oxide-Based Electrocatalytic Materials and Application in Aluminum Air Battery [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(2): 728-735.
[4]	CHEN Pu, OU Xiaoxia, ZHAO Ke, YANG Xiaoyu. Preparation of In₂S₃/g-C₃N₄ Composite Photocatalyst and Its Photocatalytic Degradation of Tetracycline [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(1): 310-318.
[5]	WU Yonglin, ZHANG Wei, DIAN Bo, CHEN Jianjun. Research Status of Phosphogypsum Pyrolysis [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(9): 3129-3137.
[6]	TONG Xin, XIONG Zhe, GAO Xinyu, HOU Junwei, LIU Yiying, LIAO Kaifeng, WU Weichuang, WU Weibin, QI Long, WANG Hailin, CAI Weizi. Research Status and Development of Proton Exchange Membrane Fuel Cell [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(9): 3243-3258.
[7]	PEI Lijie, LIU Fei, CAO Jianxin, YANG Anjie, YAO Mengqin, LIU Piao. Preparation of ZSM-5@t-ZrO₂ and Its Influence Mechanism on Catalytic Synthesis of Methanethiol [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(8): 2927-2934.
[8]	YANG Xinxin, LIU Fei, YAO Mengqin. CeO₂ Composite Modified ZSM-5 Molecular Sieve for Catalyzing Methanol to Propylene [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(7): 2549-2557.
[9]	HUO Zhiqiang, BAI Xue, TENG Yingyue, JIA Heng, SONG Yinmin, WANG Wei. Research Progress on Preparation and Photocatalytic Performance of Nanoscaled-Layered Double Hydroxides [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(4): 1440-1453.
[10]	HU Zirui, LIU Shihao, LENG Zile, ZHANG Guangxu. Regeneration Process of Fluidized Bed Complex Solution [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(12): 4389-4396.
[11]	WU Zihao, WANG Wuxiang, LIU Guangdong, WANG Aijun, ZHANG Leilei, YANG Jun. Effects of EPS Particles on Properties of Ultra-Light Cement-Based Composite Thermal Insulation Materials [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(8): 2527-2533.
[12]	YAN Ziwei, LIU Li, SUN Jinfeng, LU Bao, ZU Qinghe, ZANG Jun, LI Debiao, HOU Guihua. Synergistic Effect of Tricalcium Aluminate and Calcium Carbonate on Early Mechanical Strength and Setting Time of Portland Cement [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(5): 1470-1476.
[13]	LIU Shuai, XIE Yinde, YAN Shuo, HOU Baosen, LIU Ruijie. Preparation and Photocatalytic Properties of Composite Catalyst ZnFe₂O₄/FeVO₄ [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(5): 1707-1713.
[14]	QIN Weiyan. Synthesis of Ru Cs/Mo₂C Nanorods and Its Electrocatalytic Hydrogen Evolution [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(5): 1714-1719.
[15]	ZOU Hanjun, CHANG Qiuxiang, YANG Wenda, ZHANG Bin, GONG Xiangnan, WANG Guiwen, ZHOU Kai. Research on Electrocatalytic Hydrogen Evolution Reaction Performance of Pt-P25 Prepared by Critical Point Drier [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(2): 658-663.