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BULLETIN OF THE CHINESE CERAMIC SOCIETY ›› 2022, Vol. 41 ›› Issue (4): 1163-1169.

• Special Issue for the 2027 Glass Science and Technology Conference • Previous Articles     Next Articles

Ion-Exchange Process of Ultrathin Aluminosilicate Glasses

LIAO Weifan1, HU Chuanjie2, WANG Mingzhong3, GUO Yunlan1, CUI Xiuzhen3, LIANG Xinhui3, LIU Chao1   

  1. 1. State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China;
    2. Chongqing BOE Electronics Technology Co. Ltd., Chongqing 400799, China;
    3. Xianning Nanbo Photoelectric Glass Co. Ltd., Xianning 437000, China
  • Received:2021-11-02 Revised:2021-12-16 Online:2022-04-15 Published:2022-04-27

Abstract: High-strength ultrathin cover glass is an important part of electronic information products, and chemical strengthening (ion-exchange) is the main technological approach to improve the mechanical properties of ultrathin cover glass. During ion-exchange, stress relaxation (structural relaxation) can easily take place, making it difficult for chemically strengthened glasses to simultaneously achieve high compressive stress, large depth of layer, and high Vickers hardness. To overcome this issue, two-step ion-exchange was developed to strengthen aluminosilicate glasses. Effects of molten salts, ion-exchange temperature and duration on the distributions of stress layers and Vickers hardness were investigated. Results demonstrate that high compressive stress, large depth of layer, and high Vickers hardness can be simultaneously achieved via two-step ion-exchange. After ion-exchange, the compressive stress of the glass is over 900 MPa, the depth of layer is over 70 μm and Vickers hardness is over 7.2 GPa.

Key words: ultrathin glass, cover glass, aluminosilicate glass, ion-exchange, compressive stress, depth of layer, Vickers hardness

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