Preparation and Properties of Graphene/Glass Bulk Composites

Abstract

Abstract: An in-situ strategy for the preparation of reduced graphene oxide/sodium calcium silicon (rGO/SLS) glass bulk composites using 3-aminopropyltriethoxysilane as a surfactant was reported. GO nanosheets that were negatively charged in an aqueous solution were combined with positively charged glass particles modified by amino groups through electrostatic self-assembly to generate composite particles. Through high temperature vacuum hot press sintering, GO was reduced to rGO, and rGO/SLS bulk composites were in situ produced. Results show that rGO is evenly distributed in the glass matrix and greatly enhances the mechanical properties of rGO/SLS bulk composites. With a 0.5% (mass fraction), addition of rGO in the rGO/SLS bulk composite, the flexural strength of the composite is about double that of pure SLS glass.

Key words: reduced graphene oxide, glass, hot press sintering, mechanical property

CLC Number:

TB484.5

ZHOU Wentao, LI Jianlin. Preparation and Properties of Graphene/Glass Bulk Composites[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2020, 39(12): 3998-4002.

References

[1] Geim A K. Graphene: status and prospects[J]. Science, 2009, 324(5934): 1530-1534.
[2] Li X H, Chen J S, Wang X C, et al. A green chemistry of graphene: photochemical reduction towards monolayer graphene sheets and the role of water adlayers[J]. ChemSusChem, 2012, 5(4): 642-646.
[3] Markandan K, Chin J K, Tan M T T. Recent progress in graphene based ceramic composites: a review[J]. Journal of Materials Research, 2017, 32(1): 84-106.
[4] Fan Y C, Wang L J, Li J L, et al. Preparation and electrical properties of graphene nanosheet/Al₂O₃ composites[J]. Carbon, 2010, 48(6): 1743-1749.
[5] 兰双龙,刘树江,弋康峰.Al₂O₃含量对钠钙硅玻璃析晶行为的影响[J].硅酸盐通报,2019,38(6):1850-1854.
[6] Zhang L, Yang W B, Jiang Z N, et al. Graphene oxide-modified microencapsulated phase change materials with high encapsulation capacity and enhanced leakage-prevention performance[J]. Applied Energy, 2017, 197: 354-363.
[7] Giusca C E, Perrozzi F, Melios C, et al. Electrostatic transparency of graphene oxide sheets[J]. Carbon, 2015, 86: 188-196.
[8] 黄诗轶,夏令,宋少先.有机物对针铁矿团聚氧化石墨烯(GO)的影响[J].硅酸盐通报,2019,38(7):2329-2334.
[9] Chen B B, Liu X, Zhao X Q, et al. Preparation and properties of reduced graphene oxide/fused silica composites[J]. Carbon, 2014, 77: 66-75.
[10] Liu X, Li J L, Yu X W, et al. Graphene nanosheet/titanium carbide composites of a fine-grained structure and improved mechanical properties[J]. Ceramics International, 2016, 42(1): 165-172.
[11] Dresselhaus M S, Jorio A, Hofmann M, et al. Perspectives on carbon nanotubes and graphene Raman spectroscopy[J]. Nano Letters, 2010, 10(3): 751-758.
[12] Zhao Y, Sun K N, Wang W L, et al. Microstructure and anisotropic mechanical properties of graphene nanoplatelet toughened biphasic calcium phosphate composite[J]. Ceramics International, 2013, 39(7): 7627-7634.
[13] Fang X Y, Yu X X, Zheng H M, et al. Temperature and thickness-dependent electrical conductivity of few-layer graphene and graphene nanosheets[J]. Physics Letters, 2015, 379(37): 2245-2251.
[14] Zhou M, Lin T, Huang F, et al. Highly conductive porous graphene/ceramic composites for heat transfer and thermal energy storage[J]. Advanced Fuctional Materials, 2013, 23(18): 2263-2269.

[1]	LI Nan, XIE Zhipeng, YI Zhongzhou, ZHAI Fengrui. Research and Application Progress of Ce-Y(Ca)-TZP Ceramics and Ce-TZP/Al₂O₃ Composite Ceramics [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2020, 39(12): 3729-3742.
[2]	LI Shicai, YU Yong, JIN Zuquan. Review on Mechanical Properties and Durability of Seawater and Sea-Sand Concrete [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2020, 39(12): 3743-3752.
[3]	LI Xiaoqin, ZHOU Xu, LI Shihua. Effect of Fly Ash Content on Properties of PVA-ECC [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2020, 39(12): 3783-3790.
[4]	YANG Zhenying, ZHOU Changshun. Effect of Glass Powder on Mechanical Properties of Recycled Concrete [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2020, 39(12): 3874-3880.
[5]	LIU Zhenzheng, XIE Chunlei, WANG Xueying, GUO Liang, WU Yueyue, CHEN Qin, DUAN Ping. Preparation of Rice Husk Ash and Its Effect on Mechanical Properties of Geopolymer [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2020, 39(12): 3881-3888.
[6]	YANG Lingming, ZHANG Weixiang, ZHOU Shaoqing. Influence of Basalt Fiber on Properties of Traditional Sticky Rice-Lime Mortar and Its Mechanism Analysis [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2020, 39(12): 3924-3931.
[7]	QIAN Min, ZOU Zhaosong, TANG Jingping, JIANG Yasi, XU Yongchun, HU Lili. Development of High-Purity Dense Zircon for Melting Low-Loss Special Glasses [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2020, 39(12): 4003-4009.
[8]	YANG Lei;HE Ting-shu;GAI Guo-sheng;HE Juan;CHEN Chang. Effect of Fiber Properties on Mechanical Properties and Microstructures of Autoclaved Aerated Concrete [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2018, 37(6): 1813-1817.
[9]	ZHANG Fan;NIU Huan-huan;LI Wen;FAN Bing-bing;ZHANG Rui. Investigation on the Manufacturing Process and Properties of Ceramic Wall Brick and Floor Tile with Fly Ash [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2018, 37(6): 1941-1945.
[10]	LI Ming-yue;TIAN Zhi-yun;SHAO Jing;ZHANG Hong-bo;ZOU Xiang-yu;SU Chun-hui. Preparation and Application of Vanadate Glass-ceramic Sealing Material [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2018, 37(6): 2030-2034.
[11]	ZHANG Chun-mei;CHENG Xiao-wei;YANG Yong-sheng;GUO Xiao-yang;CHEN Zu-wei. Synthesis and Performance Study of Self-repairing Microcapsules for Micro-cracks of Oil-well Cement Matrix [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2018, 37(6): 2035-2041.
[12]	LI Xiang-guo;MING Tian;LIU Zhuo-lin;REN Zhao-feng;JIANG Wen-guang. Research on Durability and Mechanical Properties of Carbon Nanotube Cement Matrix Composites [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2018, 37(5): 1497-1502.
[13]	LI Ming;ZHANG Yan;WANG Yan-liang;LI Yong;CHEN E-qiu;YIN Xiao-peng. Research on Carbonation Depth and Mechanical Properties of Concrete of Transmission Lines in Arid Areas [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2018, 37(5): 1556-1562.
[14]	LI Yang;WANG Fei;ZHANG Qing;LI Nan. Three-dimensional Numerical Simulation of Oxy-fuel Glass Tanky [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2018, 37(5): 1578-1582.
[15]	HUANG Sai-jia. Mechanical Properties of Hydrated Calcium Silicate Simulated by Molecular Dynamics [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2018, 37(5): 1687-1692.