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BULLETIN OF THE CHINESE CERAMIC SOCIETY ›› 2010, Vol. 29 ›› Issue (1): 162-166.

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Research on Low-temperature Sintering and Properties of Ca_(0.3)(Li_(0.5)Sm_(0.5))_(0.7)TiO_3 Microwave Dielectric Ceramics with Composite Sintering Additive

ZHANG Bin;LI Yue-ming;ZHANG Hua;LIAO Run-hua   

  • Online:2010-02-15 Published:2021-01-18

Abstract: The low temperature sintering process and the microwave dielectric properties of a microwave dielectric material based on Ca_(0.3)(Li_(0.5)Sm_(0.5))_(0.7)TiO_3(CLST-0.7) ceramic with 10 wt % CaO-B_2O_3-SiO_2 (CBS) multiplicity oxide and 4 wt % Li_2O-B_2O_3-SiO_2-CaO-Al_2O_3 (LBSCA) glass and 0-2 wt% CuO multiplicity additives were investigated. The results indicate that with the increasing of CuO content, the bulk density, the dielectric constant ε_r, the product of quality factor and resonance frequency Qf value of CLST-0.7 ceramics all increase first and then decrease and the temperature coefficient of resonant frequency τ_f of CLST ceramics decrease. The sample of CLST with 10 wt% CBS, 4.0 wt% LBSCA and 1.0 wt% CuO sintered at 900 ℃ for 5 h exhibits excellent microwave dielectric properties:ε_r=67.31,Qf=2197 GHz,τ_f=40.28 ppm/℃.

Key words: Ca_(0.30(Li_(0.5)Sm_(0.5))_(0.7)TiO_3;CaO-B_2O_3-SiO_2;Li_2O-B_2O_3-SiO_2-CaO-Al_2O_3;CuO;microwave dielectric ceramic;low temperature sintering

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