基于SLA光聚合的蓝色氧化锆陶瓷制备与性能研究

doi:10.16552/j.cnki.issn1001-1625.2025.0050

硅酸盐通报 ›› 2025, Vol. 44 ›› Issue (8): 2977-2987.DOI: 10.16552/j.cnki.issn1001-1625.2025.0050

基于SLA光聚合的蓝色氧化锆陶瓷制备与性能研究

祝佳豪^1,2, 陈盛贵^3,4, 梁嘉华⁵, 覃家塔^1,2, 李楠⁶, 周柱坤^1,2

1.广西大学机械工程学院,南宁 530004;
2.广西大学省部共建特色金属材料与组合结构全寿命安全国家重点实验室,南宁 530004;
3.广州番禺职业技术学院艺术设计学院,广州 511483;
4.深圳永昌和科技有限公司,深圳 518103;
5.东莞市东莞理工科技创新研究院,东莞 523808;
6.东莞理工学院教育学院(师范学院),东莞 523808

收稿日期:2025-01-10 修订日期:2025-03-31 出版日期:2025-08-15 发布日期:2025-08-22
通信作者: 周柱坤,博士,讲师。E-mail:zhukunzhou@gxu.edu.cn
作者简介:祝佳豪(2001—),男,硕士研究生。主要从事陶瓷3D打印方面的研究。E-mail:jiahao828z@163.com
基金资助:
广东省教育厅普通高校重点科研项目(2023WCXTD035);阳江市省科技创新战略专项(SDZX2023019);广州番禺职业技术学院科研项目(2023KJ04)

Preparation and Properties of Blue Zirconia Ceramics Based on SLA Photopolymerization

ZHU Jiahao^1,2, CHEN Shenggui^3,4, LIANG Jiahua⁵, QIN Jiata^1,2, LI Nan⁶, ZHOU Zhukun^1,2

1. School of Mechanical Engineering, Guangxi University, Nanning 530004, China;
2. State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures, Guangxi University, Nanning 530004, China;
3. School of Art and Design, Guangzhou Panyu Polytechnic, Guangzhou 511483, China;
4. Shenzhen Yongchanghe Technology Co., Ltd., Shenzhen 518103, China;
5. Dongguan Institute of Science and Technology Innovation, Dongguan 523808, China;
6. School of Education (Teachers College), Dongguan University of Technology, Dongguan 523808, China

Received:2025-01-10 Revised:2025-03-31 Published:2025-08-15 Online:2025-08-22

摘要/Abstract

摘要： 彩色氧化锆陶瓷因具有可调控的色彩、较好的机械加工性和较强的稳定性,可广泛应用于手机背板、高端装饰材料等高科技领域。本研究制备了三种不同Co₃O₄含量,总固含量为55%(体积分数)的蓝色氧化锆陶瓷膏料,并成功将其用于立体光刻(SLA)光聚合打印。结果表明,与未着色的陶瓷样品相比,添加少量Co₃O₄会使陶瓷样品的抗弯强度略微提升。烧结后的平均晶粒尺寸随着Co₃O₄含量的增加而增大,陶瓷样品中的单斜相结构逐渐增多。并且对蓝色氧化锆陶瓷样品的致色机理进行了研究,随着Co₃O₄含量的增加,陶瓷样品在可蓝光范围(435~490 nm)内的反射率出现明显下降,当Co₃O₄含量为1.0%(质量分数)时,所获陶瓷样品的机械性能和光学性能最佳。陶瓷样品的抗弯强度和维氏硬度,明显优于同类研究的结果。本研究实现了使用蓝色陶瓷材料打印整体式可移动部件,该部件具有高精度和优越性能,为高端装饰材料领域打印高强度结构提供了可能。

关键词: 立体光刻, 氧化锆, 陶瓷膏料, 蓝色陶瓷, 致色机理, 机械性能

Abstract: Colored zirconia ceramics can be widely used in high-tech fields such as mobile phone backplanes and high-end decorative materials due to their adjustable color, good mechanical processing and strong stability. In this study, three blue zirconia ceramic pastes with different Co₃O₄ content and a total solid content of 55% (volume fraction) were prepared and successfully used for stereolithography (SLA) photopolymerization printing. The results show that the addition of a small amount of Co₃O₄ slightly improves the flexural strength of the ceramic samples compared with the uncolored samples. The average grain size after sintering increases with the increase of Co₃O₄ content, and the monoclinic phase structure in the ceramic samples gradually increases. And the chromogenic mechanism of the blue zirconia ceramic samples is investigated, with the increase of Co₃O₄ content, the reflectance of the ceramic samples in the blua light range (435~490 nm) appeares to be significantly decreased. When the Co₃O₄ content is 1.0% (mass fraction), the mechanical and optical properties of the obtained samples are the best. The flexural strength and Vickers hardness of the ceramic samples are significantly better than those obtain in previous studies. This study has realized the use of blue ceramic materials to print monolithic movable parts, and this parts achieve high precision and superior performance, providing the possibility of printing high-strength structures in the field of high-end decorative materials.

Key words: stereolithography, zirconia, ceramic paste, blue ceramics, chromogenic mechanism, mechanical property

中图分类号:

TQ174.75

祝佳豪, 陈盛贵, 梁嘉华, 覃家塔, 李楠, 周柱坤. 基于SLA光聚合的蓝色氧化锆陶瓷制备与性能研究[J]. 硅酸盐通报, 2025, 44(8): 2977-2987.

ZHU Jiahao, CHEN Shenggui, LIANG Jiahua, QIN Jiata, LI Nan, ZHOU Zhukun. Preparation and Properties of Blue Zirconia Ceramics Based on SLA Photopolymerization[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(8): 2977-2987.

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基于SLA光聚合的蓝色氧化锆陶瓷制备与性能研究

Preparation and Properties of Blue Zirconia Ceramics Based on SLA Photopolymerization

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