(ZrMg)xY2-2xW3O12陶瓷的制备及热膨胀性能研究

硅酸盐通报 ›› 2024, Vol. 43 ›› Issue (11): 4195-4200.

(ZrMg)_xY_2-2xW₃O₁₂陶瓷的制备及热膨胀性能研究

王献立, 王海丽, 许坤, 段向阳, 陈冬霞

郑州航空工业管理学院材料学院,郑州 450046

收稿日期:2024-03-27 修订日期:2024-07-13 出版日期:2024-11-15 发布日期:2024-11-21
通信作者: 陈冬霞,博士,副教授。E-mail:chendx1982@163.com
作者简介:王献立(1986—),男,助理实验师。主要从事负热膨胀材料的研究。E-mail:wangxianli@zua.edu.cn
基金资助:
河南省自然科学基金(222300420578);河南高校重点科研项目基础研究专项计划(22ZX012);河南省重点研发与推广专项(科技攻关)(222102320345)

Preparation and Thermal Expansion Properties of (ZrMg)_xY_2-2xW₃O₁₂ Ceramics

WANG Xianli, WANG Haili, XU Kun, DUAN Xiangyang, CHEN Dongxia

School of Materials Science and Engineering, Zhengzhou University of Aeronautics, Zhengzhou 450046

Received:2024-03-27 Revised:2024-07-13 Published:2024-11-15 Online:2024-11-21

摘要/Abstract

摘要： 采用固相烧结法制备出(ZrMg)_xY_2-2xW₃O₁₂(x=0、0.1、0.2、0.3、0.4、0.5、0.6、0.7、0.8、0.9和1.0)陶瓷,并利用X射线衍射、拉曼光谱、热分析仪及热膨胀仪分析材料的结构、吸水性及热膨胀性能。结果表明,随着Zr⁴⁺/Mg²⁺含量的增加,(ZrMg)_xY_2-2xW₃O₁₂的吸水性明显降低,热膨胀系数由负热膨胀逐渐变为正热膨胀,且逐渐增大。当x=0.6时,(ZrMg)_0.6Y_0.8W₃O₁₂(455~1 050 K,-0.54×10^-6 K^-1)展示出近零膨胀性,a、b、c轴的热膨胀系数分别为α_a=-1.13×10^-6 K^-1、α_b=1.77×10^-6 K^-1和α_c=-1.80×10^-6 K^-1,本征体积热膨胀系数α_v=-1.21×10^-6 K^-1。

关键词: (ZrMg)_xY_2-2xW₃O₁₂, 负热膨胀, 热膨胀系数, 吸水性, 固相烧结法

Abstract: (ZrMg)_xY_2-2xW₃O₁₂ (x=0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9 and 1.0) ceramics were developed with a simple solid state method, and the structure, hygroscopicity and thermal expansion property of ceramics were characterized by X-ray diffraction, Raman spectroscopy, thermal analyzer and thermal dilatometer. The results show that with the increase of Zr⁴⁺/Mg²⁺ content, the hygrosopicity of (ZrMg)_xY_2-2xW₃O₁₂ ceramics decreases obviously, and the coefficient of thermal expansion increases gradually from negative thermal expansion to positive thermal expansion. A near-zero thermal expansion is realized for (ZrMg)_0.6Y_0.8W₃O₁₂ (455~1 050 K,-0.54×10^-6 K^-1) as x=0.6, and the coefficient of thermal expansion of a, b and c axes are measured to be α_a=-1.13×10^-6 K^-1, α_b=1.77×10^-6 K^-1 and α_c=-1.80×10^-6 K^-1, respectively. The intrinsic volumetric coefficient of thermal expansion α_v is -1.21×10^-6 K^-1.

Key words: (ZrMg)_xY_2-2xW₃O₁₂, negative thermal expansion, coefficient of thermal expansion, hygrosopicity, solid state method

中图分类号:

TQ174

王献立, 王海丽, 许坤, 段向阳, 陈冬霞. (ZrMg)_xY_2-2xW₃O₁₂陶瓷的制备及热膨胀性能研究[J]. 硅酸盐通报, 2024, 43(11): 4195-4200.

WANG Xianli, WANG Haili, XU Kun, DUAN Xiangyang, CHEN Dongxia. Preparation and Thermal Expansion Properties of (ZrMg)_xY_2-2xW₃O₁₂ Ceramics[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(11): 4195-4200.

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(ZrMg)_xY_2-2xW₃O₁₂陶瓷的制备及热膨胀性能研究

Preparation and Thermal Expansion Properties of (ZrMg)_xY_2-2xW₃O₁₂ Ceramics

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