CaBi4Ti4O15-Bi(Fe0.93Mn0.05Ti0.02)O3铁电固溶体薄膜的制备及储能特性

硅酸盐通报 ›› 2024, Vol. 43 ›› Issue (6): 2301-2309.

CaBi₄Ti₄O₁₅-Bi(Fe_0.93Mn_0.05Ti_0.02)O₃铁电固溶体薄膜的制备及储能特性

余致尧, 王文文, 司景翔, 苑秀芳, 李成龙, 林秀娟, 杨长红

济南大学山东省建筑材料制备与测试技术重点实验室,济南 250022

收稿日期:2023-10-20 修订日期:2023-12-11 出版日期:2024-06-15 发布日期:2024-06-18
通信作者: 杨长红,博士,教授。E-mail:mse_yangch@ujn.edu.cn
作者简介:余致尧(1999—),男,硕士研究生。主要从事铁电薄膜材料的研究。E-mail:973690515@qq.com
基金资助:
国家自然科学基金面上项目(51972144);山东省重点研发计划(2022CXPT045);济南市“高校20条”项目(T202009)

Preparation and Energy Storage Properties of CaBi₄Ti₄O₁₅-Bi(Fe_0.93Mn_0.05Ti_0.02)O₃ Ferroelectric Solid Solution Thin Films

YU Zhiyao, WANG Wenwen, SI Jingxiang, YUAN Xiufang, LI Chenglong, LIN Xiujuan, YANG Changhong

Shandong Provincial Key Laboratory of Preparation and Measurement of Building Materials, University of Jinan, Jinan 250022, China

Received:2023-10-20 Revised:2023-12-11 Online:2024-06-15 Published:2024-06-18

摘要/Abstract

摘要： 采用金属有机分解法结合旋涂技术,在Pt(111)/TiO₂/SiO₂/Si衬底上制备(1-x)CaBi₄Ti₄O₁₅-xBi(Fe_0.93Mn_0.05Ti_0.02)O₃(CBT-xBFMT,x=0,0.05,0.10,0.15)固溶体薄膜,通过X-射线衍射仪、场发射扫描电子显微镜、铁电分析仪和阻抗分析仪,系统研究了CBT基薄膜的储能性能。结果表明,所制备的薄膜均呈现出多晶铋层状结构,无杂相生成。BFMT的引入增大了薄膜的最大极化强度P_m和抗击穿场强E_b,并降低了漏电流密度。随着BFMT固溶量的增加,CBT-xBFMT薄膜的抗击穿场强E_b先增大后减小,在x=0.10处达到最大;最大极化强度P_m逐渐增加,在x=0.10处极化强度差最大;最大抗击穿场强和最大极化强度差的共同作用使CBT-0.10BFMT薄膜具有最佳储能特性,有效储能密度W_rec和储能效率η分别为82.8 J/cm³和78.3%,且储能稳定性(25~150 ℃)良好。CBT-0.10BFMT铁电薄膜有望应用于环境友好型小型能量储存器件。

关键词: CaBi₄Ti₄O₁₅薄膜, 固溶体, 介电储能, 击穿场强, 极化强度差, 高温

Abstract: (1-x)CaBi₄Ti₄O₁₅-xBi(Fe_0.93Mn_0.05Ti_0.02)O₃(CBT-xBFMT, x=0, 0.05, 0.10, 0.15) solid solution films were successfully prepared on Pt(111)/TiO₂/SiO₂/Si substrates using metal organic decomposition combined with spin coating technology. And the energy storage properties of CBT thin films were systematically studied by X-ray diffractometer, field emission scanning electron microscope, ferroelectric analyzer and impedance analyzer. The results show that the prepared films all exhibit a polycrystalline bismuth layered structure without other phase formation. The addition of BFMT into thin film obviously enhances the maximum polarization strength P_m and breakdown field strength E_b, reduces the leakage current density. With the increase of BFMT solid solution, the breakdown field strength E_b of CBT-xBFMT film increases first and then decreases, and reaches the maximum value at x=0.10. The maximum polarization strength P_m gradually increases, and the largest polarization strength difference is obtained at x=0.10. The largest polarization intensity difference and breakdown field strength make CBT-0.10BFMT film has the best energy storage properties. The recoverable energy storage density W_rec and energy storage efficiency η of CBT-0.10BFMT film are up to 82.8 J/cm³ and 78.3%, respectively. And its energy storage characteristic has good temperature stability in the temperature range of 25~150 ℃. Therefore, CBT-0.10BFMT ferroelectric film is expected to be used in environmentally friendly micro energy storage devices.

Key words: CaBi₄Ti₄O₁₅ thin film, solid solution, dielectric energy storage, electric breakdown field, polarization intensity difference, high temperature

中图分类号:

TN384

余致尧, 王文文, 司景翔, 苑秀芳, 李成龙, 林秀娟, 杨长红. CaBi₄Ti₄O₁₅-Bi(Fe_0.93Mn_0.05Ti_0.02)O₃铁电固溶体薄膜的制备及储能特性[J]. 硅酸盐通报, 2024, 43(6): 2301-2309.

YU Zhiyao, WANG Wenwen, SI Jingxiang, YUAN Xiufang, LI Chenglong, LIN Xiujuan, YANG Changhong. Preparation and Energy Storage Properties of CaBi₄Ti₄O₁₅-Bi(Fe_0.93Mn_0.05Ti_0.02)O₃ Ferroelectric Solid Solution Thin Films[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(6): 2301-2309.

参考文献

[1] HE Q F, SUN K, SHI Z C, et al. Polymer dielectrics for capacitive energy storage: from theories, materials to industrial capacitors[J]. Materials Today, 2023, 68: 298-333.
[2] WANG Z P, KANG R R, ZHANG L X, et al. Ultrahigh energy-storage capacity achieved in (Bi_0.5Na_0.5)TiO₃-based high-entropy dielectric capacitors with linear-like polarization response[J]. Chemical Engineering Journal, 2023, 474: 145506.
[3] RITAMÄKI M, RYTÖLUOTO I, LAHTI K, et al. Large-area approach to evaluate DC electro-thermal ageing behavior of BOPP thin films for capacitor insulation systems[J]. IEEE Transactions on Dielectrics and Electrical Insulation, 2017, 24(2): 826-836.
[4] GUO X Y, YUAN X F, WANG W W, et al. Multilayer structured CaBi₄Ti₄O₁₅ thin film capacitor with excellent energy storage performance[J]. Journal of Materials Science: Materials in Electronics, 2023, 34(4): 337.
[5] PAN H, ZENG Y, SHEN Y, et al. BiFeO₃-SrTiO₃ thin film as a new lead-free relaxor-ferroelectric capacitor with ultrahigh energy storage performance[J]. Journal of Materials Chemistry A, 2017, 5(12): 5920-5926.
[6] PAN H, LI F, LIU Y, et al. Ultrahigh-energy density lead-free dielectric films via polymorphic nanodomain design[J]. Science, 2019, 365(6453): 578-582.
[7] PAN Z B, WANG P, HOU X, et al. Fatigue-free aurivillius phase ferroelectric thin films with ultrahigh energy storage performance[J]. Advanced Energy Materials, 2020, 10(31): 2001536.
[8] PAN H, MA J, MA J, et al. Giant energy density and high efficiency achieved in bismuth ferrite-based film capacitors via domain engineering[J]. Nature Communications, 2018, 9: 1813.
[9] ZHANG Y L, LI W L, CAO W P, et al. Mn doping to enhance energy storage performance of lead-free 0. 7NBT-0. 3ST thin films with weak oxygen vacancies[J]. Applied Physics Letters, 2017, 110(24): 243901.
[10] ZHANG Y L, LI W L, QIAO Y L, et al. 0.6ST-0.4NBT thin film with low level Mn doping as a lead-free ferroelectric capacitor with high energy storage performance[J]. Applied Physics Letters, 2018, 112(9): 093902.
[11] LI P, CHEN X Q, WANG F F, et al. Microscopic insight into electric fatigue resistance and thermally stable piezoelectric properties of (K, Na)NbO₃-based ceramics[J]. ACS Applied Materials & Interfaces, 2018, 10(34): 28772-28779.
[12] YANG C H, HU G D, WU W B, et al. Reduced leakage current, enhanced ferroelectric and dielectric properties in (Ce, Fe)-codoped Na_0.5Bi_0.5TiO₃ film[J]. Applied Physics Letters, 2012, 100(2): 022909.
[13] HUANG Y H, WANG J J, YANG T N, et al. A thermodynamic potential, energy storage performances, and electrocaloric effects of Ba_1-i>xSr_xTiO₃ single crystals[J]. Applied Physics Letters, 2018, 112(10): 102901.
[14] WANG J J, WU P P, MA X Q, et al. Temperature-pressure phase diagram and ferroelectric properties of BaTiO₃ single crystal based on a modified Landau potential[J]. Journal of Applied Physics, 2010, 108(11): 114105.
[15] TANG Z H, CHEN J Y, YANG B, et al. Energy storage performances regulated by layer selection engineering for doping in multi-layered perovskite relaxor ferroelectric films[J]. Applied Physics Letters, 2019, 114(16): 163901.
[16] YANG B B, GUO M Y, TANG X W, et al. Lead-free A₂Bi₄Ti₅O₁₈ thin film capacitors (A=Ba and Sr) with large energy storage density, high efficiency, and excellent thermal stability[J]. Journal of Materials Chemistry C, 2019, 7(7): 1888-1895.
[17] YANG B B, GUO M Y, JIN L H, et al. Ultrahigh energy storage in lead-free BiFeO₃/Bi_3.25La_0.75Ti₃O₁₂ thin film capacitors by solution processing[J]. Applied Physics Letters, 2018, 112(3): 033904.
[18] AL-WREIKAT Y, SERRANO C, SODRÉ J R. Effects of ambient temperature and trip characteristics on the energy consumption of an electric vehicle[J]. Energy, 2022, 238: 122028.
[19] WATSON J, CASTRO G. High-temperature electronics pose design and reliability challenges[J]. Analog Dialogue, 2012, 46(2): 2-27.
[20] WATSON J, CASTRO G. A review of high-temperature electronics technology and applications[J]. Journal of Materials Science: Materials in Electronics, 2015, 26(12): 9226-9235.
[21] HENGST S, LUONG-VAN D M, EVERETT J R, et al. A small, high-efficiency diesel generator for high-altitude use in Antarctica[J]. International Journal of Energy Research, 2009, 34(9): 827-838.

CaBi₄Ti₄O₁₅-Bi(Fe_0.93Mn_0.05Ti_0.02)O₃铁电固溶体薄膜的制备及储能特性

Preparation and Energy Storage Properties of CaBi₄Ti₄O₁₅-Bi(Fe_0.93Mn_0.05Ti_0.02)O₃ Ferroelectric Solid Solution Thin Films

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	甘学彧, 陈帅, 耿海宁, 李宗刚, 马浩森, 陈伟, 侯硕, 李秋. 改性高浓度硼酸溶液对蛇纹石屏蔽混凝土力学性能与中子屏蔽性能的影响[J]. 硅酸盐通报, 2024, 43(6): 2047-2055.
[2]	李罗胤, 董水博, 刘海峰, 雍雯洁, 车佳玲. 沙漠砂混凝土高温后强度预测及超声检测研究[J]. 硅酸盐通报, 2024, 43(6): 2073-2083.
[3]	王发静, 王新杰, 朱平华, 刘啸林. 粗骨料取代率对机制砂再生混凝土高温性能的影响[J]. 硅酸盐通报, 2024, 43(6): 2084-2092.
[4]	罗伊明, 张博, 刘彦钰, 吴守军, 付国. 混杂纤维增强超高性能混凝土的高温性能试验研究[J]. 硅酸盐通报, 2024, 43(3): 825-832.
[5]	郭子荣, 杨鼎宜, 曹忠露, 贾向锋, 赵健, 陈龙祥, 毛翔. 混掺纤维水泥砂浆的高温性能研究[J]. 硅酸盐通报, 2024, 43(3): 851-865.
[6]	冷玲倻, 张鹏飞, 梁文文. 高温下玄武岩纤维增强地质聚合物混凝土的动态压缩力学行为[J]. 硅酸盐通报, 2024, 43(3): 914-921.
[7]	庞建勇, 郑瑞琪, 胡秀月, 孙健, 徐国平, 苏永强. 高温后冷却方式对玄武岩纤维混凝土力学性能的影响[J]. 硅酸盐通报, 2024, 43(1): 92-101.
[8]	刘浩, 胡娟, 金清平, 李帆, 张新胜, 杨曌, 廖宜顺. 高温蒸汽养护复掺混凝土力学性能时变特性与模型研究[J]. 硅酸盐通报, 2024, 43(1): 227-235.
[9]	刘文进, 周国相, 杨治华, 贾德昌. 高温下氮化硅陶瓷摩擦磨损性能的演变及机理研究[J]. 硅酸盐通报, 2024, 43(1): 302-311.
[10]	孙楚函, 王洪磊, 周新贵. 前驱体转化法制备超高温陶瓷粉体研究进展[J]. 硅酸盐通报, 2023, 42(8): 2865-2880.
[11]	谭金奇, 信彩丽, 屠恒勇, 韩壮壮, 刘冰, 袁坚. Na₂O对固体氧化物燃料电池用透辉石封接微晶玻璃性能的影响[J]. 硅酸盐通报, 2023, 42(8): 2922-2927.
[12]	田英良, 袁智淳, 徐博, 穆广涵, 赵志永. 澄清剂对废液晶玻璃熔制耐热玻璃的影响[J]. 硅酸盐通报, 2023, 42(8): 2928-2935.
[13]	何娅兰, 宁麟, 李炀, 钟秀杰. 基于核磁共振技术对水泥砂浆高温后孔隙结构及水分迁移特征的研究[J]. 硅酸盐通报, 2023, 42(7): 2336-2343.
[14]	杨昭, 石建军, 许新春, 张志恒. 蛇纹石混凝土研究应用进展[J]. 硅酸盐通报, 2023, 42(6): 1912-1920.
[15]	陈曦平, 王诏田, 罗洪杰, 程岩, 吴林丽, 姜昊. 粉煤灰基多孔地聚物的结构及过滤性能[J]. 硅酸盐通报, 2023, 42(6): 2081-2091.