Na2O-CaO-SiO2平板玻璃减反射功能化研究

硅酸盐通报 ›› 2024, Vol. 43 ›› Issue (4): 1366-1373.

• “玻璃材料与玻璃技术”专题(II) • 上一篇下一篇

Na₂O-CaO-SiO₂平板玻璃减反射功能化研究

郝霞¹, 王其琛², 符有杰¹, 李军葛¹, 赵会峰¹, 姜宏^1,2, 王卓³

1.海南海控特玻科技有限公司,澄迈 571924;
2.海南大学,海南省特种玻璃重点实验室,海口 570100;
3.山东轻工职业学院,淄博 255000

收稿日期:2023-12-08 修订日期:2024-01-31 出版日期:2024-04-15 发布日期:2024-04-17
通信作者: 王卓,博士。E-mail:wangzhuosust@163.com
作者简介:郝霞(1991—),女。主要从事玻璃表面改性方面的研究。E-mail:904240081@qq.com
基金资助:
海南省重大科技计划(ZDKJ2021049)

Anti-Reflection Functionalization of Na₂O-CaO-SiO₂ Flat Glass

HAO Xia¹, WANG Qichen², FU Youjie¹, LI Junge¹, ZHAO Huifeng¹, JIANG Hong^1,2, WANG Zhuo³

1. Hainan Holdings Special Glass Technology Co., Ltd., Chengmai 571924, China;
2. Special Glass Key Lab of Hainan Province, Hainan University, Haikou 570100, China;
3. Shangdong Vocational College of Light Industry, Zibo 255000, China

Received:2023-12-08 Revised:2024-01-31 Online:2024-04-15 Published:2024-04-17

摘要/Abstract

摘要： 随着光伏产业的高速发展,与之配套使用的减反射玻璃重新进入了研究者们的视野。本文采用湿化学二步刻蚀法制备了具有减反射性能的Na₂O-CaO-SiO₂平板玻璃,采用分光光度计、扫描电子显微镜、原子力显微镜和X射线能谱仪等测试样品的透过率、表面形貌和断面膜层厚度、表面化学成分、耐酸性和硬度,研究了反应温度和反应时间、玻璃膜层结构与透过率的关系。通过使用弱碱性的混合盐溶液对Na₂O-CaO-SiO₂玻璃表面进行化学刻蚀,使玻璃表面Si—O键断裂,在玻璃表面形成纳米膜层结构,当膜层厚度达到一定厚度时,一定波长的光在玻璃表面发生相消干涉,透过率最高可达到97.8%,刻蚀前后玻璃成分基本无变化,铅笔硬度达到3H。

关键词: 减反射玻璃, 透过率, Na₂O-CaO-SiO₂平板玻璃, 湿化学二步刻蚀法, 表面微裂纹, 纳米孔

Abstract: With the rapid development of photovoltaic industry in recent years, anti-reflective glass comes into researchers' sight. This article uses two-step chemical etching method to prepare Na₂O-CaO-SiO₂ flat glass with anti-reflective properties. The transmittance, surface morphology, cross-section film thickness, surface chemical composition, acid resistance and hardness of samples were measured by spectrophotometer, scanning electron microscope, atomic force microscope and X-ray energy spectrometer. The relationship between reaction temperature, reaction time, glass film structure and transmittance were studied. The Si—O bonds on Na₂O-CaO-SiO₂ flat glass surface were broken by etching glass surface with weakly alkaline mixed salt solution, and a nano film structure is formed on the surface of glass. When the corrosion reaches a certain thickness, destructive interference of a certain wavelength of light occurs on glass surface, with a maximum transmittance of 97.8%. The glass composition remains basically unchanged before and after etching, and the pencil hardness reaches 3H.

Key words: anti-reflection glass, transmittance, Na₂O-CaO-SiO₂ flat glass, wet chemical two-step etching method, surface micro-crack, crack extension

中图分类号:

TQ171

郝霞, 王其琛, 符有杰, 李军葛, 赵会峰, 姜宏, 王卓. Na₂O-CaO-SiO₂平板玻璃减反射功能化研究[J]. 硅酸盐通报, 2024, 43(4): 1366-1373.

HAO Xia, WANG Qichen, FU Youjie, LI Junge, ZHAO Huifeng, JIANG Hong, WANG Zhuo. Anti-Reflection Functionalization of Na₂O-CaO-SiO₂ Flat Glass[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(4): 1366-1373.

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Na₂O-CaO-SiO₂平板玻璃减反射功能化研究

Anti-Reflection Functionalization of Na₂O-CaO-SiO₂ Flat Glass

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