m(ZnO)/m(B2O3)质量比对低熔点封接玻璃Bi2O3-B2O3-ZnO结构、性能与润湿性的影响

硅酸盐通报 ›› 2024, Vol. 43 ›› Issue (4): 1341-1349.

• “玻璃材料与玻璃技术”专题(II) • 上一篇下一篇

m(ZnO)/m(B₂O₃)质量比对低熔点封接玻璃Bi₂O₃-B₂O₃-ZnO结构、性能与润湿性的影响

康涛¹, 熊春荣¹, 符有杰², 蔡邦辉³, 魏曙光¹, 李军葛², 姜宏^1,2

1.海南大学,海南省特种玻璃重点实验室,海口 570228;
2.海南海控特玻科技有限公司,澄迈 571924;
3.四川英诺维新材料科技有限公司,达州 635107

收稿日期:2023-09-07 修订日期:2024-01-15 出版日期:2024-04-15 发布日期:2024-04-17
通信作者: 姜宏,博士,教授。E-mail:jhong63908889@sina.com
作者简介:康涛(1995—),男,硕士研究生。主要从事特种玻璃粉的研究。E-mail:162064410@qq.com
基金资助:
国家自然科学基金(U22A20124);海南大学海洋科技协同创新中心项目(XTCX2022HYC26)

Effect of m(ZnO)/m(B₂O₃) Mass Ratio on Structure, Properties and Wettability of Low Melting Point Sealing Glass Bi₂O₃-B₂O₃-ZnO

KANG Tao¹, XIONG Chunrong¹, FU Youjie², CAI Banghui³, WEI Shuguang¹, LI Junge², JIANG Hong^1,2

1. Hainan Key Laboratory of Special Glass, Hainan University, Haikou 570228, China;
2. Hainan Haichentebo Technology Co., Ltd., Chengmai 571924, China;
3. Sichuan Innove New Material Technology Co., Ltd., Dazhou 635107, China

Received:2023-09-07 Revised:2024-01-15 Online:2024-04-15 Published:2024-04-17

摘要/Abstract

摘要： 针对真空玻璃封接的性能要求,本文采用高温熔融法制备了一种针对真空玻璃封接的铋系非晶无铅玻璃粉,通过高温X射线衍射、粉末X射线衍射、拉曼光谱、差式扫描量热仪、热膨胀测试和扫描电子显微镜等测试方法,研究了m(ZnO)/m(B₂O₃)质量比对Bi₂O₃-B₂O₃-ZnO玻璃的网络结构、特征温度、热膨胀系数和封接温度的影响。结果表明,增加m(ZnO)/m(B₂O₃)质量比可促进锌氧多面体由[ZnO₄]向[ZnO₆]转变,导致热膨胀系数降低,特征温度升高。当m(Bi₂O₃) ∶m(B₂O₃) ∶m(ZnO)质量比为80 ∶7 ∶13, 玻璃具有较低的玻璃化转变温度T_g(371 ℃)和膨胀软化温度T_f(401 ℃),热膨胀系数为 9.3×10^-6 ℃^-1,封接温度为450 ℃,可满足真空玻璃封接对低熔点封接玻璃粉的要求。

关键词: m(ZnO)/m(B₂O₃)质量比, 特征温度, Bi₂O₃-B₂O₃-ZnO玻璃, 真空玻璃, 封接温度, 封接玻璃粉

Abstract: Aiming at the performance requirements of vacuum glass sealing, a bismuth-based amorphous lead-free glass powder for vacuum glass sealing was prepared by high temperature melting method. The effects of m(ZnO)/m(B₂O₃) mass ratio on network structure, characteristic temperature, coefficient of thermal expansion and sealing temperature of Bi₂O₃-B₂O₃-ZnO glass were studied by high temperature X-ray diffraction, powder X-ray diffraction, Raman spectroscopy, differential scanning calorimeter, thermal expansion test and scanning electron microscope. The results show that increasing m(ZnO)/m(B₂O₃) mass ratio can promote the transformation of zinc-oxygen polyhedron from [ZnO₄] to [ZnO₆], resulting in a decrease in the coefficient of thermal expansion and an increase in the characteristic temperature. When m(Bi₂O₃) ∶m(B₂O₃) ∶m(ZnO) mass ratio is 80 ∶7 ∶13, the glass has lower glass transition temperature T_g (371 ℃) and expansion softening temperature T_f (401 ℃), the coefficient of thermal expansion is 9.3×10^-6 ℃^-1, and the sealing temperature is 450 ℃, which can meet the requirements of vacuum glass sealing for low melting point sealing glass powder.

Key words: m(ZnO)/m(B₂O₃) mass ratio, characteristic temperature, Bi₂O₃-B₂O₃-ZnO glass, vacuum glass, sealing temperature, sealing glass powder

中图分类号:

TQ171

康涛, 熊春荣, 符有杰, 蔡邦辉, 魏曙光, 李军葛, 姜宏. m(ZnO)/m(B₂O₃)质量比对低熔点封接玻璃Bi₂O₃-B₂O₃-ZnO结构、性能与润湿性的影响[J]. 硅酸盐通报, 2024, 43(4): 1341-1349.

KANG Tao, XIONG Chunrong, FU Youjie, CAI Banghui, WEI Shuguang, LI Junge, JIANG Hong. Effect of m(ZnO)/m(B₂O₃) Mass Ratio on Structure, Properties and Wettability of Low Melting Point Sealing Glass Bi₂O₃-B₂O₃-ZnO[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(4): 1341-1349.

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m(ZnO)/m(B₂O₃)质量比对低熔点封接玻璃Bi₂O₃-B₂O₃-ZnO结构、性能与润湿性的影响

Effect of m(ZnO)/m(B₂O₃) Mass Ratio on Structure, Properties and Wettability of Low Melting Point Sealing Glass Bi₂O₃-B₂O₃-ZnO

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