Li2O/Na2O对YAS微晶玻璃结构、析晶与力学性能的影响

硅酸盐通报 ›› 2024, Vol. 43 ›› Issue (4): 1292-1300.

• “玻璃材料与玻璃技术”专题(II) • 上一篇下一篇

Li₂O/Na₂O对YAS微晶玻璃结构、析晶与力学性能的影响

郑伟宏, 刘国凤, 张浩, 王启东, 张梦豪, 袁坚

武汉理工大学硅酸盐建筑材料国家重点实验室,武汉 430070

收稿日期:2023-11-22 修订日期:2024-01-08 出版日期:2024-04-15 发布日期:2024-04-17
通信作者: 张浩,硕士研究生。E-mail:haohaoren2021@163.com
作者简介:郑伟宏(1981—),男,博士,副教授。主要从事电子玻璃/微晶玻璃方面的研究。E-mail:zhengweihong@whut.edu.cn
基金资助:
硅酸盐国家重点实验室(武汉理工大学)开放基金(2011DA105356)

Effect of Li₂O/Na₂O on Structure, Crystallization and Mechanical Properties of YAS Glass-Ceramics

ZHENG Weihong, LIU Guofeng, ZHANG Hao, WANG Qidong, ZHANG Menghao, YUAN Jian

State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China

Received:2023-11-22 Revised:2024-01-08 Online:2024-04-15 Published:2024-04-17

摘要/Abstract

摘要： 透明微晶玻璃由于优异的力学性能被广泛应用于电子领域。本文采用熔融法制备了不同质量分数Li₂O和Na₂O的Y₂O₃-Al₂O₃-SiO₂(YAS)微晶玻璃,通过Raman、DSC、XRD、FESEM、UV-VIS-NIR等测试方法研究了其结构特征、析晶与力学性能。结果表明:当碱金属氧化物R₂O(R=Li,Na)总量保持不变,随着Li₂O取代Na₂O含量的增加,YAS微晶玻璃的转变温度、软化温度和结晶峰温度逐渐降低,Q⁴基团对应的含量逐渐减少,说明Li₂O作为网络外体使YAS微晶玻璃结构逐步解聚,玻璃的析晶能力逐渐增强。在同一热处理制度下,随着Li₂O取代量的增加,YAS微晶玻璃维氏硬度显著提升,而透过率明显下降。在680 ℃/10 h+750 ℃/1 h热处理制度下,可以制备出晶体大小一致且分布均匀的以钇稳定氧化锆为主晶相的透明YAS微晶玻璃,此时2%(质量分数,下同)Na₂O+4%Li₂O YAS微晶玻璃具有良好的综合性能,如维氏硬度为646 HV,断裂韧性为1.07 MPa·m^1/2,透过率为85.7%,在诸多领域具有巨大的应用潜力。

关键词: Y₂O₃-Al₂O₃-SiO₂, 透明微晶玻璃, 碱金属氧化物, 结构, 析晶, 维氏硬度

Abstract: Transparent glass-ceramics are widely used in the electronic field due to their excellent mechanical properties. Y₂O₃-Al₂O₃-SiO₂ (YAS) glass-ceramics with different mass fractions of Li₂O and Na₂O were prepared by melting method, and the structural characteristics, crystallization and mechanical properties were investigated by Raman, DSC, XRD, FESEM, UV-VIS-NIR. The results show that when the total content of R₂O (R=Li, Na) remains unchanged, the transition temperature, softening temperature and crystallization peak temperature of YAS glass-ceramics decrease as the content of Li₂O replacing Na₂O increases, the content of structure units Q⁴ gradually decreases, indicating that Li₂O as a network modifier gradually depolymerizes the structure of YAS glass-ceramics and promotes the crystallization ability of glass. It is also found that with the increase of Li₂O content, the Vickers hardness of YAS glass-ceramics increases significantly, while the transmittance decreases significantly at the same heat treatment. Under the heat treatment at 680 ℃ for 10 h and 750 ℃ for 1 h, YAS glass-ceramics with uniform crystal size and distribution and yttrium stabilized zirconia as the main crystalline phase can be prepared. At present, YAS glass-ceramics containing 2% (mass fraction,the same below)Na₂O and 4% Li₂O exhibits favorable overall performance. The Vickers hardness is 646 HV, the fracture toughness is 1.07 MPa·m^1/2 and the transmittance is 85.7%, which has great potential for many applications.

Key words: Y₂O₃-Al₂O₃-SiO₂, transparent glass-ceramics, alkali metal oxide, structure, crystallization, Vickers hardness

中图分类号:

TQ171

郑伟宏, 刘国凤, 张浩, 王启东, 张梦豪, 袁坚. Li₂O/Na₂O对YAS微晶玻璃结构、析晶与力学性能的影响[J]. 硅酸盐通报, 2024, 43(4): 1292-1300.

ZHENG Weihong, LIU Guofeng, ZHANG Hao, WANG Qidong, ZHANG Menghao, YUAN Jian. Effect of Li₂O/Na₂O on Structure, Crystallization and Mechanical Properties of YAS Glass-Ceramics[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(4): 1292-1300.

参考文献

[1] VOMACKA P, BABUSHKIN O. Yttria-alumina-silica glasses with addition of zirconia[J]. Journal of the European Ceramic Society, 1995, 15(9): 921-928.
[2] ZHENG Q S, LIU Y C, LI M, et al. Crystallization behavior and IR structure of yttrium aluminosilicate glasses[J]. Journal of the European Ceramic Society, 2020, 40(2): 463-471.
[3] 卢安贤, 王宇, 肖卓豪. 碱金属氧化物对MgO-Al₂O₃-SiO₂系统微晶玻璃析晶和性能的影响[J]. 中南大学学报(自然科学版), 2008, 39(1): 42-47.
LU A X, WANG Y, XIAO Z H. Effects of alkalis on crystallization and properties of MgO-Al₂O₃-SiO₂ system glass ceramics[J]. Journal of Central South University (Science and Technology), 2008, 39(1): 42-47 (in Chinese).
[4] 章璐娴, 何峰, 梅书霞, 等. Li₂O对硼硅酸盐玻璃结构与性能的影响[J]. 武汉理工大学学报, 2015, 37(5): 15-20.
ZHANG L X, HE F, MEI S X, et al. Effect of Li₂O on structure and property of borosilicate glass[J]. Journal of Wuhan University of Technology, 2015, 37(5): 15-20 (in Chinese).
[5] MONEY B K, HARIHARAN K. Mixed alkali effect on crystallization kinetics of xNa₂O ∶(50-x)Li₂O ∶50P₂O₅[J]. Solid State Ionics, 2014, 262: 824-828.
[6] 王乾晨, 王静, 韩建军, 等. Li₂O对Li₂O-Al₂O₃-SiO₂系低热膨胀微晶玻璃析晶行为的影响[J]. 材料科学与工程学报, 2019, 37(4): 541-545+577.
WANG Q C, WANG J, HAN J J, et al. Effects of Li₂O on the crystallization behavior of Li₂O-Al₂O₃-SiO₂ glass-ceramics with low thermal expansion[J]. Journal of Materials Science and Engineering, 2019, 37(4): 541-545+577 (in Chinese).
[7] 曾麟, 黄守佳, 林鸿剑, 等. 混合碱效应对Li₂O-Al₂O₃-SiO₂系玻璃结构和热膨胀性能的影响[J]. 硅酸盐通报, 2021, 40(11): 3813-3821.
ZENG L, HUANG S J, LIN H J, et al. Influence of mixed alkali effect on structure and thermal expansion properties of Li₂O-Al₂O₃-SiO₂ glass[J]. Bulletin of the Chinese Ceramic Society, 2021, 40(11): 3813-3821 (in Chinese).
[8] HOU Y, ZHANG G H, CHOU K C. Mixed alkali effect in SiO₂-CaO-Al₂O₃-TiO₂-R₂O (R=Li, Na) glass ceramics[J]. Journal of Alloys and Compounds, 2021, 856: 158239.
[9] HE Y, SHEN X F, JIANG Y, et al. Effects of Li₂O replacing Na₂O on glass forming, structure and properties of Na₂O-MgO-Al₂O₃-SiO₂ glass and glass-ceramics[J]. Materials Chemistry and Physics, 2021, 258: 123865.
[10] 刘玉成. 氮、氟掺杂对钇铝硅酸盐玻璃结构与性能的影响[D]. 包头: 内蒙古科技大学, 2020.
LIU Y C. Effect of nitrogen and fluorine doping on structure and properties of yttrium aluminosilicate glass[D]. Baotou: Inner Mongolia University of Science & Technology, 2020 (in Chinese).
[11] ZHAO J L, LU Y D, KANG J F, et al. Effect of Y₂O₃ and La₂O₃ on structure and dielectric properties of aluminoborosilicate glasses[J]. Journal of Non-Crystalline Solids, 2018, 496: 1-5.
[12] ZHU W W, JIANG H F, ZHANG H, et al. Effect of TiO₂ and CaF₂ on the crystallization behavior of Y₂O₃-Al₂O₃-SiO₂ glass ceramics[J]. Ceramics International, 2018, 44(6): 6653-6658.
[13] ARNAULT L, GERLAND M, RIVIÈRE A. Microstructural study of two LAS-type glass-ceramics and their parent glass[J]. Journal of Materials Science, 2000, 35(9): 2331-2345.
[14] WILKINSON C J, POTTER A R, WELCH R S, et al. Topological origins of the mixed alkali effect in glass[J]. The Journal of Physical Chemistry B, 2019, 123(34): 7482-7489.
[15] CALAHOO C, XIA Y, ZHOU R. Influence of glass network ionicity on the mixed-alkali effect[J]. International Journal of Applied Glass Science, 2020, 11(3): 396-414.
[16] WANG M T, ZHENG Q S, CHEN A Y, et al. Crystallization, thermal expansion and hardness of Y₂O₃-Al₂O₃-SiO₂ glasses[J]. Ceramics International, 2021, 47(17): 25059-25066.
[17] MIYATA N, JINNO H. Discussion of the indentation hardness of a glass-ceramic with participate microstructure[J]. Journal of Materials Science, 1982, 17(9): 2693-2699.

编辑推荐

Metrics

阅读次数

全文

HTML			PDF

最新录用	在线预览	正式出版	最新录用	在线预览	正式出版
0	0	0	0	0	90

来源	本网站	其他网站

次数	89	1
比例	99%	1%

摘要

最新录用	在线预览	正式出版

0	0	75

	来源	本网站

	次数	75
	比例	100%

Li₂O/Na₂O对YAS微晶玻璃结构、析晶与力学性能的影响

Effect of Li₂O/Na₂O on Structure, Crystallization and Mechanical Properties of YAS Glass-Ceramics

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	朱晓岗, 黄艳萍, 黄文浩, 卢佳妍, 刘毅. 光伏镀膜玻璃研究进展及发展趋势[J]. 硅酸盐通报, 2024, 43(4): 1211-1218.
[2]	尚楷浡, 李铭涵, 李军葛, 马艳平, 姜宏, 赵亚军, 张吉亮, 董闯. 基于团簇加连接原子模型的一种工业微晶玻璃成分优化初探[J]. 硅酸盐通报, 2024, 43(4): 1257-1266.
[3]	卫志洋, 王晓东, 苏腾, 陈欢乐, 高峰, 苗洋. CaO-B₂O₃-SiO₂微晶玻璃的制备及介电性能[J]. 硅酸盐通报, 2024, 43(4): 1274-1283.
[4]	蒲博洋, 廖其龙, 王辅, 古雨鑫, 胥有利, 竹含真. Fe₂O₃对含铈钙钛矿玻璃陶瓷物相结构及化学稳定性的影响[J]. 硅酸盐通报, 2024, 43(4): 1308-1317.
[5]	李宁, 赵立革, 赵少伟, 王卉, 郑永超. Ti含量对矿渣玻璃体结构及其水化活性的影响机制研究[J]. 硅酸盐通报, 2024, 43(4): 1325-1334.
[6]	毛婧怡, 刘冰, 郭振强, 张家昌, 袁坚. 柔性玻璃的化学强化及其力学性能研究[J]. 硅酸盐通报, 2024, 43(4): 1359-1365.
[7]	张兵强, 霍宏越, 石攀, 王三昭, 任宏宇, 刘启蒙. 光吸收玻璃对耐辐照光纤面板性能的影响[J]. 硅酸盐通报, 2024, 43(4): 1374-1379.
[8]	张全红, 王涛, 穆松, 蔡佳豪, 刘凯, 周莹, 刘光严. 不同侵蚀环境下喷射混凝土耐久性提升技术及作用机理[J]. 硅酸盐通报, 2024, 43(4): 1410-1419.
[9]	刘佳敏, 马玉薇, 李刚. 粉煤灰对渠道用混凝土抗冻及抗冲磨性能的影响[J]. 硅酸盐通报, 2024, 43(4): 1436-1444.
[10]	吕亚军, 宋彩红, 党钧陶, 董宾宾, 乔敏, 张康捷, 马肖峰. 两种耐水处理长余辉材料制备发光混凝土的性能对比研究[J]. 硅酸盐通报, 2024, 43(3): 781-792.
[11]	李兆睿, 王振军, 张海宝, 张亚明, 张松林, 张博伦. 三乙醇胺和硬脂酸锌对泡沫混凝土性能的影响[J]. 硅酸盐通报, 2024, 43(3): 793-805.
[12]	刘富强, 马芹永. 纤维素-玄武岩混杂纤维喷射混凝土力学性能及能量演化[J]. 硅酸盐通报, 2024, 43(3): 806-815.
[13]	罗伊明, 张博, 刘彦钰, 吴守军, 付国. 混杂纤维增强超高性能混凝土的高温性能试验研究[J]. 硅酸盐通报, 2024, 43(3): 825-832.
[14]	郭子荣, 杨鼎宜, 曹忠露, 贾向锋, 赵健, 陈龙祥, 毛翔. 混掺纤维水泥砂浆的高温性能研究[J]. 硅酸盐通报, 2024, 43(3): 851-865.
[15]	阎培渝, 刘宇. 矿物掺合料对复合胶凝材料浆体静态屈服应力的影响[J]. 硅酸盐通报, 2024, 43(3): 922-928.