组成对钠铝硅玻璃中钇锆酸盐纳米晶析晶性能的影响

硅酸盐通报 ›› 2024, Vol. 43 ›› Issue (2): 710-718.

所属专题：玻璃

组成对钠铝硅玻璃中钇锆酸盐纳米晶析晶性能的影响

田英良, 韩金龙, 徐博, 温玉琳, 李培浩, 何峰, 赵志永

北京工业大学材料与制造学部,北京 100124

收稿日期:2023-03-28 修订日期:2023-05-10 出版日期:2024-02-15 发布日期:2024-02-05
通信作者: 赵志永,博士。E-mail:zhaozhiyong@bjut.edu.cn
作者简介:田英良(1969—),男,博士,教授。主要从事新型玻璃材料方面的研究。E-mail:tianyl@bjut.edu.cn
基金资助:
北京市教委科研计划科技一般项目(KM202210005008)

Effect of Composition on Crystallization Properties of Yttrium Zirconate Nanocrystals in Sodium-Aluminum-Silicate Glass

TIAN Yingliang, HAN Jinlong, XU Bo, WEN Yulin, LI Peihao, HE Feng, ZHAO Zhiyong

Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing 100124, China

Received:2023-03-28 Revised:2023-05-10 Online:2024-02-15 Published:2024-02-05

摘要/Abstract

摘要： 基于含Y₂O₃和ZrO₂的钠铝硅玻璃体系,研究了玻璃组分中Al₂O₃/Na₂O摩尔比值(M_AN)与SiO₂/Al₂O₃摩尔比值(M_SA)对玻璃析晶性能的影响。研究结果表明,当M_AN <1时,玻璃经热处理后表面析出钠霞石晶体;当M_AN ≥1时,玻璃热处理后析出钇锆酸盐纳米晶体,且此时微晶玻璃仍然具有不小于90%的高可见光透过率。对于固定M_AN的玻璃,调整其M_SA也能实现钇锆酸盐纳米晶的析出,且析出晶体尺寸随M_SA增加而减小。随着热处理温度升高微晶玻璃样品中纳米晶体尺寸增大,维氏硬度也增大。

关键词: 钠铝硅玻璃, 析晶行为, 热处理, 钇锆酸盐纳米晶, 透明微晶玻璃, 维氏硬度

Abstract: The influences of the molar ratios of Al₂O₃/Na₂O (M_AN) and SiO₂/Al₂O₃ (M_SA)on the crystallization properties of the glass were studied in this work based on the sodium-aluminum-silicate glass system containing Y₂O₃ and ZrO₂. The results show that, when M_AN<1, sodium nepheline crystals precipitate on the surface of the glass after heat treatment. When M_AN>1, yttrium zirconate nanocrystals can be formed in the whole bulk glass, and the glass-ceramics can maintain a high visible light transmittance of 90%. For glass with fixed M_AN, adjusting its M_SA can also achieve the precipitation of yttrium zirconate nanocrystals, and the size of the precipitated crystals decreases as M_SA increases. Furthermore, as the heat treatment temperature rises, the size of nanocrystals in glass-ceramic nanocrystals as well as Vickers hardness increases.

Key words: sodium-aluminum-silicate glass, crystallization behavior, heat treatment, yttrium zirconate nanocrystal, transparent glass-ceramics, Vickers hardness

中图分类号:

TQ171

田英良, 韩金龙, 徐博, 温玉琳, 李培浩, 何峰, 赵志永. 组成对钠铝硅玻璃中钇锆酸盐纳米晶析晶性能的影响[J]. 硅酸盐通报, 2024, 43(2): 710-718.

TIAN Yingliang, HAN Jinlong, XU Bo, WEN Yulin, LI Peihao, HE Feng, ZHAO Zhiyong. Effect of Composition on Crystallization Properties of Yttrium Zirconate Nanocrystals in Sodium-Aluminum-Silicate Glass[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(2): 710-718.

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组成对钠铝硅玻璃中钇锆酸盐纳米晶析晶性能的影响

Effect of Composition on Crystallization Properties of Yttrium Zirconate Nanocrystals in Sodium-Aluminum-Silicate Glass

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