热激励去极化电流技术在无机材料中的应用

硅酸盐通报 ›› 2023, Vol. 42 ›› Issue (7): 2579-2588.

所属专题：陶瓷

热激励去极化电流技术在无机材料中的应用

张效华^1,2, 张寓涛¹, 张杰², 施赟舟², 曲海默², 张力², 张曜², 骆宇², 卞帅帅², 郭蔚嘉², 陈雨谷², 岳振星²

1.陕西科技大学材料科学与工程学院,西安 710021;
2.清华大学材料学院,新型陶瓷与精细工艺国家重点实验室,北京 100084

收稿日期:2023-02-03 修订日期:2023-04-25 出版日期:2023-07-15 发布日期:2023-07-25
通信作者: 岳振星,教授。E-mail:yuezhx@mail.tsinghua.edu.cn
作者简介:张效华(1980—),男,博士,教授。主要从事电子信息功能材料、功能电介质与元器件、微波介质与微波吸收、功能薄膜与厚膜材料等方向的研究。E-mail:zhangcity@126.com
基金资助:
国家自然科学基金(52273315);陕西省教育厅科技项目(21JT003);清华大学新型陶瓷与精细工艺国家重点实验室开放课题(KF202212);景德镇市科技计划项目(20192GYZD008-17)

Application of Thermally Stimulated Depolarization Current Technique in Inorganic Materials

ZHANG Xiaohua^1,2, ZHANG Yutao¹, ZHANG Jie², SHI Yunzhou², QU Haimo², ZHANG Li², ZHANG Yao², LUO Yu², BIAN Shuaishuai², GUO Weijia², CHEN Yugu², YUE Zhenxing²

1. School of Materials Science and Engineering, Shaanxi University of Science & Technology, Xi'an 710021, China;
2. State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China

Received:2023-02-03 Revised:2023-04-25 Online:2023-07-15 Published:2023-07-25

摘要/Abstract

摘要： 热激励去极化电流(TSDC)测量技术可以提供存在于材料体系中的缺陷类型信息,例如空间电荷、偶极子、陷阱电荷等。通过TSDC谱分析,可研究偶极子和可动离子的性质,以及激活能、弛豫时间、荷电粒子浓度等微观参数,进而更好地理解与缺陷有关的物理本质。本文介绍了当前TSDC技术在无机材料中的应用现状,整理归纳出TSDC技术在线性介质、非线性介质、陶瓷-聚合物复合材料中的研究结果与最新进展,从本质上揭示无机材料中缺陷与性能之间的内在关联。有望拓展TSDC技术在无机材料中的应用,为无机材料微观机制研究提供新思路。

关键词: 无机材料, 热激励去极化电流, TSDC, 缺陷, 线性介质, 非线性介质, 陶瓷-聚合物复合材料

Abstract: Thermally stimulated depolarization current technique can provide information on defect types that exist in the material systems, such as space charges, dipoles, trap charges and so on. Through TSDC spectral analysis, the properties of dipoles and movable ions, as well as activation energy, relaxation time and charged particle concentration, and other microscopic parameters, can be investigated to better understand the physical nature related to defects. This paper introduces the current application status of TSDC technique in inorganic materials reported at home and abroad. The research results and recent developments of TSDC technique in linear dielectrics, nonlinear dielectrics and ceramic polymer composites are summarized, in order to reveal the inner correlation between defects and properties in inorganic materials. It is expected to expand the application of TSDC technique in inorganic materials and provide new insight for the research on the microscopic mechanism of inorganic materials.

Key words: inorganic material, thermally stimulated depolarization current, TSDC, defect, linear dielectric, nonlinear dielectric, ceramic polymer composite

中图分类号:

TB32

张效华, 张寓涛, 张杰, 施赟舟, 曲海默, 张力, 张曜, 骆宇, 卞帅帅, 郭蔚嘉, 陈雨谷, 岳振星. 热激励去极化电流技术在无机材料中的应用[J]. 硅酸盐通报, 2023, 42(7): 2579-2588.

ZHANG Xiaohua, ZHANG Yutao, ZHANG Jie, SHI Yunzhou, QU Haimo, ZHANG Li, ZHANG Yao, LUO Yu, BIAN Shuaishuai, GUO Weijia, CHEN Yugu, YUE Zhenxing. Application of Thermally Stimulated Depolarization Current Technique in Inorganic Materials[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(7): 2579-2588.

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热激励去极化电流技术在无机材料中的应用

Application of Thermally Stimulated Depolarization Current Technique in Inorganic Materials

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