核桃壳粉为碳源制备C@ZrSiO4黑色色料

硅酸盐通报 ›› 2023, Vol. 42 ›› Issue (2): 657-665.

所属专题：资源综合利用

核桃壳粉为碳源制备C@ZrSiO₄黑色色料

王济伟¹, 李家科¹, 刘欣¹, 江和栋¹, 郭平春¹, 朱华², 王艳香¹

1.景德镇陶瓷大学材料科学与工程学院,景德镇 333403;
2.景德镇陶瓷大学机械电子工程学院,景德镇 333403

收稿日期:2022-10-07 修订日期:2022-10-31 出版日期:2023-02-15 发布日期:2023-03-07
通信作者: 李家科,博士,教授。E-mail:jiakeli.jci@163.com
作者简介:王济伟(1998—),男,硕士研究生。主要从事硅酸盐材料方面的研究。E-mail:843365961@qq.com
基金资助:
江西省重点研发计划(20181BBE58004);景德镇市科技计划(20224GY008-11)

Preparation of C@ZrSiO₄ Black Pigment by Walnut Shell Powder as Carbon Source

WANG Jiwei¹, LI Jiake¹, LIU Xin¹, JIANG Hedong¹, GUO Pingchun¹, ZHU Hua², WANG Yanxiang¹

1. School of Materials Science and Engineering, Jingdezhen Ceramic University, Jingdezhen 333403, China;
2. School of Mechanical and Electronic Engineering, Jingdezhen Ceramic University, Jingdezhen 333403, China

Received:2022-10-07 Revised:2022-10-31 Online:2023-02-15 Published:2023-03-07

摘要/Abstract

摘要： 以核桃壳粉、八水氧氯化锆(ZrOCl₂·8 H₂O)和正硅酸乙酯(TEOS)等为原料,采用溶胶-沉淀法制备了硅酸锆包裹炭黑(C@ZrSiO₄)黑色色料。通过TG-DSC、FT-IR、XRD、SEM、TEM等对试样的热效应、化学结构、物相组成和微观结构进行了表征,研究了不同热处理温度、核桃壳粉/硅酸锆质量比(理论合成,下同)等对色料组成和色度的影响规律。结果表明,当热处理温度为1 100 ℃、核桃壳粉/硅酸锆质量比为1:3时,合成的C@ZrSiO₄色料发色性能最佳,L^*=31.3、a^*=+1.4和b^*=+1.3;在透明釉中外加5%(质量分数)C@ZrSiO₄色料,经1 200 ℃烧成所制备的黑釉具有较好的呈色效果,其色度值L^*=41.2、a^*=+1.2和b^*=+1.7。

关键词: 核桃壳粉, 溶胶-沉淀法, C@ZrSiO₄色料, 物相组成, 微观结构, 呈色性能

Abstract: Zirconium silicate encapsulated carbon (C@ZrSiO₄) black pigment was prepared by sol-precipitation method, using walnut shell powder, zirconium oxychloride (ZrOCl₂·8H₂O) and ethyl silicate (TEOS), etc. as raw materials. The heat effect, chemical structure, phase composition and microstructure of samples were investigated by TG-DSC, FT-IR, XRD, SEM and TEM.The effects of different heat treatment temperatures and mass ratios of walnut shell powder/ZrSiO₄(theoretical synthesis, the same below) on the phase composition and chromaticity value of pigment were studied. The results show that the C@ZrSiO₄ pigment with excellent coloring performance (L^*=31.3, a^*=+1.4 and b^*=+1.3) can be obtained when heat treatment temperature is 1 100 ℃, and the mass ratio of walnut shell powder/ZrSiO₄ is 1:3. When 5% (mass fraction) C@ZrSiO₄ is added to transparent glaze under firing temperature of 1 200 ℃, the black glaze exhibits excellent coloring performance with the color value of L^*=41.2, a^*=+1.2 and b^*=+1.7.

Key words: walnut shell powder, sol-precipitation method, C@ZrSiO₄ pigment, phase composition, microstructure, chromatic performance

中图分类号:

TQ174.4

王济伟, 李家科, 刘欣, 江和栋, 郭平春, 朱华, 王艳香. 核桃壳粉为碳源制备C@ZrSiO₄黑色色料[J]. 硅酸盐通报, 2023, 42(2): 657-665.

WANG Jiwei, LI Jiake, LIU Xin, JIANG Hedong, GUO Pingchun, ZHU Hua, WANG Yanxiang. Preparation of C@ZrSiO₄ Black Pigment by Walnut Shell Powder as Carbon Source[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(2): 657-665.

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核桃壳粉为碳源制备C@ZrSiO₄黑色色料

Preparation of C@ZrSiO₄ Black Pigment by Walnut Shell Powder as Carbon Source

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