Ti3C2Tx/Ni/TiO2复合粉体的制备及吸波性能研究

硅酸盐通报 ›› 2021, Vol. 40 ›› Issue (1): 296-303.

所属专题：新型功能材料

Ti₃C₂T_x/Ni/TiO₂复合粉体的制备及吸波性能研究

杜恒¹, 张帆^1,2, Shen Gang³, Qaim Khan¹, 凡康康¹, 张碧晗¹, 李宁¹, 范冰冰¹, 张锐^1,4

1.郑州大学材料科学与工程学院,郑州 450001;
2.河南信息统计职业学院建筑工程系,郑州 450000;
3.布里斯托大学土木工程学院,布里斯托 BS8 1TR;
4.郑州航空工业管理学院材料科学与工程学院,郑州 450015

收稿日期:2020-08-20 修回日期:2020-10-03 出版日期:2021-01-15 发布日期:2021-02-07
通讯作者: 范冰冰,博士,副教授。E-mail:bingbing197@163.com
作者简介:杜恒(1996—),男,硕士研究生。主要从事吸波材料方面的研究。E-mail:duhengnba@163.com
基金资助:
河南省高等学校重点科研项目计划(20A430001)

Preparation and Electromagnetic Wave Absorption Properties ofTi₃C₂T_x/Ni/TiO₂ Composite Powder

DU Heng¹, ZHANG Fan^1,2, SHEN Gang³, QAIM Khan¹, FAN Kangkang¹, ZHANG Bihan¹, LI Ning¹, FAN Bingbing¹, ZHANG Rui^1,4

1. School of Materials Science and Engineering,Zhengzhou University,Zhengzhou 450001,China;
2. Department of Construction Engineering,Henan Vocational College of Information and Statistics,Zhengzhou 450000,China;
3. Department of Civil Engineering,University of Bristol,Bristol,BS8 1TR,UK;
4. School of Materials Science and Engineering,Zhengzhou University of Aeronautics,Zhengzhou 450015,China

Received:2020-08-20 Revised:2020-10-03 Online:2021-01-15 Published:2021-02-07

摘要/Abstract

摘要： 采用热处理的方法制备出二维层状Ti₃C₂T_x/Ni/TiO₂复合粉体,并利用TG-DSC、SEM、XRD和XPS对样品进行表征分析,通过矢量网络分析仪测试样品的电磁参数并模拟计算不同涂层厚度下样品的反射损耗值(RL)。结果表明:随着热处理温度的升高,样品中TiO₂质量含量增加;当热处理温度为300 ℃时,在频率f=17.5 GHz下样品的RL为-35.2 dB,其有效吸波带宽超过1.7 GHz,对应的涂层厚度为4 mm。其优异的吸波性能一方面来自良好的阻抗匹配,另外一方面来自样品的介电损耗、磁损耗的协同效应。此外,样品的电磁波吸收能力可以通过其组分和微观结构进行调控。

关键词: MXene, Ti₃C₂T_x二维层状结构, Ti₃C₂T_x/Ni/TiO₂复合粉体, 热处理, 吸波

Abstract: A two-dimensional layered Ti₃C₂T_x/Ni/TiO₂ composite powder was prepared by the heat treatment method.The samples were characterized and analyzed by TG-DSC,SEM,XRD and XPS.The electromagnetic parameters of the composite were measured by a vector network analyzer and its reflection loss(RL) under different coating thicknesses were calculated.The results show that the TiO₂ mass content in the product gradually increases as the heat treatment temperature increases.When the heat treatment temperature reaches 300 ℃,RL of the sample is -35.2 dB at f=17.5 GHz,and its effective absorption amplitude exceeds 1.7 GHz,corresponding to the thickness is 4 mm,and its excellent electromagnetic wave absorption performance due to the good impedance matching and the synergistic effect of the dielectric loss and magnetic loss of the sample.In addition,the sample electromagnetic wave absorption ability is modeled by their composition and microstructure.

Key words: MXene, two-dimensional layered Ti₃C₂T_x, Ti₃C₂T_x/Ni/TiO₂ composite powder, heat treatment, electromagnetic wave absorption

中图分类号:

TB321

杜恒, 张帆, Shen Gang, Qaim Khan, 凡康康, 张碧晗, 李宁, 范冰冰, 张锐. Ti₃C₂T_x/Ni/TiO₂复合粉体的制备及吸波性能研究[J]. 硅酸盐通报, 2021, 40(1): 296-303.

DU Heng, ZHANG Fan, SHEN Gang, QAIM Khan, FAN Kangkang, ZHANG Bihan, LI Ning, FAN Bingbing, ZHANG Rui. Preparation and Electromagnetic Wave Absorption Properties ofTi₃C₂T_x/Ni/TiO₂ Composite Powder[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(1): 296-303.

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Ti₃C₂T_x/Ni/TiO₂复合粉体的制备及吸波性能研究

Preparation and Electromagnetic Wave Absorption Properties ofTi₃C₂T_x/Ni/TiO₂ Composite Powder

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