硅酸盐通报 ›› 2021, Vol. 40 ›› Issue (1): 25-33.
所属专题: 水泥混凝土
李树鹏, 金祖权, 熊传胜
收稿日期:
2020-08-18
修回日期:
2020-09-02
出版日期:
2021-01-15
发布日期:
2021-02-07
通讯作者:
金祖权,教授。E-mail:jinzuquan@126.com
作者简介:
李树鹏(1995—),男,硕士研究生。主要从事无机非金属材料方面的研究。E-mail:1390838473@qq.com
基金资助:
LI Shupeng, JIN Zuquan, XIONG Chuansheng
Received:
2020-08-18
Revised:
2020-09-02
Online:
2021-01-15
Published:
2021-02-07
摘要: 电化学除氯(ECE)技术通过在外加阳极和钢筋阴极之间施加电压来排除氯离子使钢筋重新恢复钝化,从而达到保护钢筋混凝土的目的。为了进一步了解电化学除氯技术的发展,本文综述了近年来国内外钢筋混凝土电化学除氯技术的研究进展,阐述了电化学除氯原理,总结了电化学除氯的影响因素,系统地介绍了电化学除氯对钢筋混凝土粘结力、宏观性能和微观结构的影响,分析了目前电化学除氯存在的问题并提出了未来的研究方向,以期电化学除氯技术在提高滨海混凝土结构耐久性方面发挥更好地作用。
中图分类号:
李树鹏, 金祖权, 熊传胜. 钢筋混凝土电化学除氯技术研究现状[J]. 硅酸盐通报, 2021, 40(1): 25-33.
LI Shupeng, JIN Zuquan, XIONG Chuansheng. Research Status of Electrochemical Chloride Extraction Technology ofReinforced Concrete[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(1): 25-33.
[1] SHI X M,XIE N,FORTUNE K,et al.Durability of steel reinforced concrete in chloride environments:an overview[J].Construction and Building Materials,2012,30:125-138. [2] MEHTA P K,BURROWS R W.Building durable structures in the 21stcentury[J].Indian Concrete Journal,2001,75(7):437-443. [3] TRITTHAT J,PETTERSSON K,SORENSEN B.Electrochemical removal of chloride from hardened cement paste[J].Cement and Concrete Research,1993,23(5):1095-1104. [4] 金伟良,吴航通,许 晨,等.钢筋混凝土结构耐久性提升技术研究进展[J].水利水电科技进展,2015,35(5):68-76+135. JIN W L,WU H T,XU C,et al.Advances in research of technologies for durability enhancement of reinforced concrete structures[J].Advances in Science and Technology of Water Resources,2015,35(5):68-76+135 (in Chinese). [5] TISSIER Y,BOUTEILLER V,MARIE-VICTOIRE E,et al.Electrochemical chloride extraction to repair combined carbonated and chloride contaminated reinforced concrete[J].Electrochimica Acta,2019,317:486-493. [6] ORELLAN HERRERA J C,ESCADEILLAS G,ARLIGUIE G.Electro-chemical chloride extraction:influence of C3A of the cement on treatment efficiency[J].Cement and Concrete Research,2006,36(10):1939-1946. [7] 高小建,赵志曼,孙文博.钢筋混凝土电化学除氯原理与研究进展[J].材料导报,2007,21(5):98-101. GAO X J,ZHAO Z M,SUN W B.Mechanism and research progress of electrochemical chloride extraction on steel-reinforced concrete[J].Materials Review,2007,21(5):98-101 (in Chinese). [8] ALI M S,LEYNE E,SAIFUZZAMAN M,et al.An experimental study of electrochemical incompatibility between repaired patch concrete and existing old concrete[J].Construction and Building Materials,2018,174:159-172. [9] BENNETT J,FONG K F,SCHUE T J.Electrochemical chloride removal and protection of concrete bridge components:field trials[R].Afs Annual Meeting,1993. [10] HAY R,OSTERTAG C P.Acidification at rebar-concrete interface induced by accelerated corrosion test in aggressive chloride environment[J].Cement and Concrete Composites,2020,110:103573. [11] 王 伟,季明棠.钢筋混凝土构筑物牺牲阳极保护研究进展[J].海洋科学,2001,25(5):18-20+33. WANG W,JI M T.Review on sacrificial cathodic protection of reinforced concrete[J].Marine Sciences,2001,25(5):18-20+33 (in Chinese). [12] IHEKWABA N M,HOPE B B,HANSSON C M.Structural shape effect on rehabilitation of vertical concrete structures by ECE technique[J].Cement and Concrete Research,1996,26(1):165-175. [13] SCHNECK U,WINKLER T,GRÜNZIG H.Chloride extraction from reinforced concrete-a new defined way of application[M]//Corrosion of Reinforcement in Concrete.Amsterdam:Elsevier,2007:263-276. [14] MARCOTTE T D,HANSSON C M,HOPE B B.The effect of the electrochemical chloride extraction treatment on steel-reinforced mortar Part I:electrochemical measurements[J].Cement and Concrete Research,1999,29(10):1555-1560. [15] JIN Z Q,HOU D S,ZHAO T J.Electrochemical chloride extraction (ECE) based on the high performance conductive cement-based composite anode[J].Construction and Building Materials,2018,173:149-159. [16] 屈 锋,孙浩然,雷智昊,等.不同因素下钢筋混凝土电化学除氯效率研究[J].腐蚀科学与防护技术,2019,31(5):515-520. QU F,SUN H R,LEI Z H,et al.Effect of several processing factors on electrochemical dechlorination efficiency of reinforced concrete[J].Corrosion Science and Protection Technology,2019,31(5):515-520 (in Chinese). [17] YEIH W,CHANG J J,HUNG C C.Selecting an adequate procedure for the electrochemical chloride removal[J].Cement and Concrete Research,2006,36(3):562-570. [18] XU J,LI F M.Numerical analysis on efficiency of electrochemical chloride extraction of one side anode in concrete[J].Ocean Engineering,2019,179:38-50. [19] WANG Y,LI L Y,PAGE C L.A two-dimensional model of electrochemical chloride removal from concrete[J].Computational Materials Science,2001,20(2):196-212. [20] LIN H,LI Y,LI Y Q.A study on the deterioration of interfacial bonding properties of chloride-contaminated reinforced concrete after electrochemical chloride extraction treatment[J].Construction and Building Materials,2019,197:228-240. [21] SARASWATHY V,LEE H S,KARTHICK S,et al.Extraction of chloride from chloride contaminated concrete through electrochemical method using different anodes[J].Construction and Building Materials,2018,158:549-562. [22] CASTELLOTE M,ANDRADE C,ALONSO C.Electrochemical removal of chlorides:modelling of the extraction,resulting profiles and determination of the efficient time of treatment[J].Cement and Concrete Research,2000,30(4):615-621. [23] LIU Q F,XIA J,EASTERBROOK D,et al.Three-phase modelling of electrochemical chloride removal from corroded steel-reinforced concrete[J].Construction and Building Materials,2014,70:410-427. [24] ELSENER B,ANGST U.Mechanism of electrochemical chloride removal[J].Corrosion Science,2007,49(12):4504-4522. [25] TOUMI A,FRANCOIS R,ALVARADO O.Experimental and numerical study of electrochemical chloride removal from brick and concrete specimens[J].Cement and Concrete Research,2007,37(1):54-62. [26] ZHU J H,WEI L L,WANG Z H,et al.Application of carbon-fiber-reinforced polymer anode in electrochemical chloride extraction of steel-reinforced concrete[J].Construction and Building Materials,2016,120:275-283. [27] 高小建,郑秀梅,杨英姿.电化学参数对混凝土除氯效率的影响[J].沈阳工业大学学报,2010,32(5):579-584. GAO X J,ZHENG X M,YANG Y Z.Influence of electrochemical parameters on chloride extraction efficiency[J].Journal of Shenyang University of Technology,2010,32(5):579-584 (in Chinese). [28] PETERSEN M A,SALE T C,REARDON K F.Electrolytic trichloroethene degradation using mixed metal oxide coated titanium mesh electrodes[J].Chemosphere,2007,67(8):1573-1581. [29] TSAI W T,CHEN M S.Stress corrosion cracking behavior of 2205 duplex stainless steel in concentrated NaCl solution[J].Corrosion Science,2000,42(3):545-559. [30] SHAO Z G,LIN W F,ZHU F Y,et al.A tubular direct methanol fuel cell with Ti mesh anode[J].Journal of Power Sources,2006,160(2):1003-1008. [31] CARMONA J,GARCÉS P,CLIMENT M A.Efficiency of a conductive cement-based anodic system for the application of cathodic protection,cathodic prevention and electrochemical chloride extraction to control corrosion in reinforced concrete structures[J].Corrosion Science,2015,96:102-111. [32] CAÑÓN A,GARCÉS P,CLIMENT M A,et al.Feasibility of electrochemical chloride extraction from structural reinforced concrete using a sprayed conductive graphite powder-cement paste as anode[J].Corrosion Science,2013,77:128-134. [33] ANWAR M S,SUJITHA B,VEDALAKSHMI R.Light-weight cementitious conductive anode for impressed current cathodic protection of steel reinforced concrete application[J].Construction and Building Materials,2014,71:167-180. [34] PÉREZ A,CLIMENT M A,GARCÉS P.Electrochemical extraction of chlorides from reinforced concrete using a conductive cement paste as the anode[J].Corrosion Science,2010,52(5):1576-1581. [35] LI Y,LIU X F,WU M K,et al.Research of electrochemical chloride extraction and reinforcement of concrete column using MPC-bonded carbon fiber reinforced plastic sheet & mesh[J].Construction and Building Materials,2017,153:436-444. [36] de ALMEIDA S L R,de MEDEIROS M H F,PEREIRA E,et al.Electrochemical chloride extraction:efficiency and impact on concrete containing 1% of NaCl[J].Construction and Building Materials,2017,145:435-444. [37] YEIH W,CHANG J J,CHANG C C,et al.Electrochemical chloride removal for reinforced concrete with steel rebar cage using auxiliary electrodes[J].Cement and Concrete Composites,2016,74:136-146. [38] ARYA C,SA'ID-SHAWQI Q,VASSIE P R W.Factors influencing electrochemical removal of chloride from concrete[J].Cement and Concrete Research,1996,26(6):851-860. [39] FAJARDO G,ESCADEILLAS G,ARLIGUIE G.Electrochemical chloride extraction (ECE) from steel-reinforced concrete specimens contaminated by “artificial” sea-water[J].Corrosion Science,2006,48(1):110-125. [40] GARCÉS P,SÁNCHEZ DE ROJAS M J,CLIMENT M A.Effect of the reinforcement bar arrangement on the efficiency of electrochemical chloride removal technique applied to reinforced concrete structures[J].Corrosion Science,2006,48(3):531-545. [41] CHANG C C,YEIH W,CHANG J J,et al.Effects of stirrups on electrochemical chloride removal efficiency[J].Construction and Building Materials,2014,68:692-700. [42] 张 军,金伟良,毛江鸿,等.混凝土梁电化学修复后的耐久性能及力学特征[J].哈尔滨工业大学学报,2020,52(8):72-80. ZHANG J,JIN W L,MAO J H,et al.Durability enhancement and mechanical properties of concrete beams after electrochemical rehabilitation[J].Journal of Harbin Institute of Technology,2020,52(8):72-80 (in Chinese). [43] ANGST U,ELSENER B,LARSEN C K,et al.Critical chloride content in reinforced concrete-A review[J].Cement and Concrete Research,2009,39(12):1122-1138. [44] 张 琨,单 炜,孙文博,等.不同因素对电化学除氯处理后混凝土残留氯离子分布的影响[J].自然灾害学报,2017,26(3):106-112. ZHANG K,SHAN W,SUN W B,et al.Impact of different factors on distribution of residual chlorion in concrete after electrochemical dechlorination treatment[J].Journal of Natural Disasters,2017,26(3):106-112 (in Chinese). [45] ELGEBALEY R,ELSHAZLY Y,ELSALAMAWY M.Role of cement type on performance change of reinforcing steel due to chloride extraction[J].Construction and Building Materials,2019,208:444-453. [46] YU L B,JIANG L H,CHU H Q,et al.Effect of electrochemical chloride removal and ground granulated blast furnace slag on the chloride binding of cement paste subjected to NaCl and Na2SO4 attack[J].Construction and Building Materials,2019,220:538-546. [47] ISMAIL M,MUHAMMAD B.Electrochemical chloride extraction effect on blended cements[J].Advances in Cement Research,2011,23(5):241-248. [48] 孙文博,高小建,杨英姿,等.不同配合比混凝土的电化学除氯效果研究[J].腐蚀科学与防护技术,2009,21(3):308-311. SUN W B,GAO X J,YANG Y Z,et al.Efficiency of electrochemical chloride extraction from concretes with different mixing proportions[J].Corrosion Science and Protection Technology,2009,21(3):308-311 (in Chinese). [49] KIM K B,HWANG J P,ANN K Y.Influence of cementitious binder on chloride removal under electrochemical treatment in concrete[J].Construction and Building Materials,2016,104:191-197. [50] CHANG J J.Bond degradation due to the desalination process[J].Construction and Building Materials,2003,17(4):281-287. [51] 冯 伟,徐金霞,蒋林华,等.有机添加剂对电化学除盐效率的影响研究[J].混凝土,2016(10):100-103+108. FENG W,XU J X,JIANG L H,et al.Influence oforganic additive on electrochemical chloride extraction efficiency[J].Concrete,2016(10):100-103+108 (in Chinese). [52] OUYANG W Z,CAO X,WANG N.A mathematical model for electrochemical chloride removal from marine cast iron artifacts[J].Acta Metallurgica Sinica (English Letters),2009,22(2):91-99. [53] UEDA T,WAKITANI K,NANASAWA A.Influence of electrolyte temperature on efficiency of electrochemical chloride removal from concrete[J].Electrochimica Acta,2012,86:23-27. [54] XIA J,LIU Q F,MAO J H,et al.Effect of environmental temperature on efficiency of electrochemical chloride removal from concrete[J].Construction and Building Materials,2018,193:189-195. [55] 姚 武,王灵芝,陈逸群.超声电化学机制对砂浆中氯离子萃取效率的影响[J].硅酸盐学报,2014,42(8):1032-1036. YAO W,WANG L Z,CHEN Y Q.Influence of sonoelectrochemical mechanism on efficiency of electrochemical chloride extraction from mortar[J].Journal of the Chinese Ceramic Society,2014,42(8):1032-1036 (in Chinese). [56] IHEKWABA N M,HOPE B B.Mechanical properties of anodic and cathodic regions of ECE treated concrete[J].Cement and Concrete Research,1996,26(5):771-780. [57] 郭育霞,贡金鑫.电化学除氯后钢筋混凝土桥墩的抗震性能[J].中国公路学报,2011,24(6):72-79. GUO Y X,GONG J X.Seismic behavior of reinforced concrete pier after electrochemical chloride extraction[J].China Journal of Highway and Transport,2011,24(6):72-79 (in Chinese). [58] ZHANG J,JIN W L,MAO J H,et al.Deterioration of static mechanical properties of RC beams due to bond damage induced by electrochemical rehabilitation[J].Construction and Building Materials,2020,237:117629. [59] SWAMY R N,MCHUGH S.Effectiveness and structural implications of electrochemical chloride extraction from reinforced concrete beams[J].Cement and Concrete Composites,2006,28(8):722-733. [60] DAI K Y,LIU C,LU D G,et al.Experimental investigation on seismic behavior of corroded RC columns under artificial climate environment and electrochemical chloride extraction:a comparative study[J].Construction and Building Materials,2020,242:118014. [61] ZHANG Q,GONG J X.Study on seismic behavior of reinforced concrete columns after ECE treatment[J].Construction and Building Materials,2014,50:549-559. [62] SIEGWART M,LYNESS J F,MCFARLAND B J,et al.The effect of electrochemical chloride extraction on pre-stressed concrete[J].Construction and Building Materials,2005,19(8):585-594. [63] MAO J H,JIN W L,ZHANG J,et al.Hydrogen embrittlement risk control of prestressed tendons during electrochemical rehabilitation based on bidirectional electro-migration[J].Construction and Building Materials,2019,213:582-591. [64] MIRANDA J M,COBO A,OTERO E,et al.Limitations and advantages of electrochemical chloride removal in corroded reinforced concrete structures[J].Cement and Concrete Research,2007,37(4):596-603. [65] 金伟良,陈佳芸,毛江鸿,等.电化学修复对钢筋混凝土结构服役性能的作用效应[J].工程力学,2016,33(2):1-10. JIN W L,CHEN J Y,MAO J H,et al.The effect of electrochemical rehabilitation on service performance of reinforced concrete structures[J].Engineering Mechanics,2016,33(2):1-10 (in Chinese). [66] CARÉ S,RAHARINAIVO A.Influence of impressed current on the initiation of damage in reinforced mortar due to corrosion of embedded steel[J].Cement and Concrete Research,2007,37(12):1598-1612. [67] 韦江雄,王新祥,郑 靓,等.电除盐中析氢反应对钢筋-混凝土粘结力的影响[J].武汉理工大学学报,2009,31(12):30-34. WEI J X,WANG X X,ZHENG L,et al.Research on the hydrogen evolution reaction and its effect on the bond strength between reinforcement and concrete during electrochemical chloride extraction[J].Journal of Wuhan University of Technology,2009,31(12):30-34 (in Chinese). [68] BUENFELD N R,BROOMFIELD J P.Influence of electrochemical chloride extraction on the bond between steel and concrete[J].Magazine of Concrete Research,2000,52(2):79-91. [69] 郑秀梅,李广军,支秀兰.电化学除盐对钢筋与混凝土间黏结力的影响[J].混凝土,2011(6):46-48+51. ZHENG X M,LI G J,ZHI X L.Effect of electrochemical chloride extraction on adhesion strength between steel bars and concrete[J].Concrete,2011(6):46-48+51 (in Chinese). [70] 郑秀梅,臧澄澄,张 皓,等.除氯后混凝土性能变化规律研究[J].低温建筑技术,2015,37(4):7-9. ZHENG X M,ZANG C C,ZHANG H,et al.Research on the change law of concrete properties after dechlorination[J].Low Temperature Architecture Technology,2015,37(4):7-9 (in Chinese). [71] 王文仲,郑秀梅,刘晓丹,等.电化学除盐对混凝土微观结构的影响[J].混凝土,2011(3):28-30+71. WANG W Z,ZHENG X M,LIU X D,et al.Influence of microscopic structure in concrete by electrochemical salt releasing[J].Concrete,2011(3):28-30+71 (in Chinese). [72] ORELLAN J C,ESCADEILLAS G,ARLIGUIE G.Electrochemical chloride extraction:efficiency and side effects[J].Cement and Concrete Research,2004,34(2):227-234. [73] 俞凯奇,毛江鸿,陈佳芸,等.混凝土电化学除氯过程钢筋周围氯离子迁移规律试验研究[J].混凝土,2015(2):33-35+42. YU K Q,MAO J H,CHEN J Y,et al.Experimental research on chloride migration regularity around steel-bar during electrochemical chloride extraction for reinforced concrete[J].Concrete,2015(2):33-35+42 (in Chinese). [74] SIEGWART M,LYNESS J F,MCFARLAND B J.Change of pore size in concrete due to electrochemical chloride extraction and possible implications for the migration of ions[J].Cement and Concrete Research,2003,33(8):1211-1221. [75] 单鸿猷,徐金霞,蒋林华.电化学除氯和硅酸根电迁移法的联合修复研究[J].材料导报,2016,30(14):1-5+14. SHAN H Y,XU J X,JIANG L H.Remediation method of combining electrochemical chloride removal with electro-migration of silicate ion[J].Materials Review,2016,30(14):1-5+14 (in Chinese). |
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