欢迎访问《硅酸盐通报》官方网站,今天是

硅酸盐通报 ›› 2018, Vol. 37 ›› Issue (2): 625-629.

• • 上一篇    下一篇

重金属离子对蒸养混凝土力学性能影响及其浸出特性研究

苏小梅;李坚   

  1. 武汉城市职业学院,武汉,430064;武汉船舶职业技术学院,武汉,430050
  • 出版日期:2018-02-15 发布日期:2021-01-18

Effects of Heavy Metal Ions on Mechanical Properties and Leaching Characteristics of Steam Curing Concrete

SU Xiao-mei;LI Jian   

  • Online:2018-02-15 Published:2021-01-18

摘要: 蒸养混凝土具有早期强度高、模具周转速度快和生产效率高等显著优势,成为混凝土预制构件主要制备工艺.通过抗压强度、离子浸出试验、X射线衍射等测试方法,研究了锌、铬、铜对蒸养混凝土的力学性能、水化产物结构及其浸出特性,并探讨了粉煤灰对蒸养混凝土固化重金属离子效果的影响规律.结果表明:①Zn、Cr和Cu离子能够在不同程度上降低蒸养混凝土的抗压强度,当掺量为1.0%时,抗压强度分别降低了50.63%、13.23%和99.27%;Zn、Cr和Cu离子不能明显改变水化产物的微观形貌,但是会抑制氢氧化钙(CH)和钙矾石的生成和结晶.②当掺量低于1.0%时,蒸养混凝土对Zn和Cr离子具有很好地固化作用,浸出浓度均小于0.21 mg/L,但是Cu离子的浸出浓度高达0.92 mg/L以上.掺加20%粉煤灰的蒸养混凝土抗压强度会降低5~8 MPa,并不能提高其对重金属离子的固化性能.

关键词: 蒸养混凝土;重金属离子;抗压强度;固化;粉煤灰

Abstract: Abstact:Considering its high early strength,mold transfer speed and production efficiency,steam curing concrete has become the main preparation technology of precast concrete.The mechanical properties,ion leaching test and X ray diffraction were used to investigated the effects of zinc,chromium and copper on the mechanical properties,hydration product structure and leaching characteristics of steam curing concrete.What~ more,the effects of fly ash on solidification of heavy metal ions by steam curing concrete was also discussed.The results show that:①Zn,Cr and Cu ions reduce the compressive strength of steam curing concrete in varying degrees.When the dosage of 1%,the compressive strength decreases by 50.63%,13.23% and 99.27%,respectively.Zn,Cr and Cu ions can not significantly change the morphology of hydration products,but can inhibit the formation and crystallization of calcium hydroxide and ettringite.②When the dosage is lower than 1%,the steam curing concrete have good solidification on Zn and Cr ions,the leaching concentration of which are less than 0.21 mg/L,but the leaching concentration of Cu ion is as high as more than 0.92 mg/L.The compressive strength of steam curing concrete added with 20% fly ash is reduced by about 5 ~8 MPa,and the solidification of heavy metal ions can not be improved.

Key words: steam curing concrete;heavy metal ion;compressive strength;solidification;fly ash

中图分类号: