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硅酸盐通报 ›› 2017, Vol. 36 ›› Issue (12): 4072-4077.

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29Si固体核磁共振技术在水泥基材料定量分析中的应用

肖建敏;李辉;党媛;胥明琳   

  1. 西安建筑科技大学材料与矿资学院,西安 710055;陕西省生态水泥混凝土工程技术研究中心,西安 710055;西安建筑科技大学理学院,西安,710055;西安建筑科技大学材料与矿资学院,西安,710055
  • 出版日期:2017-12-15 发布日期:2021-01-18
  • 基金资助:
    陕西省教育厅专项科研计划项目(16JK1446)

Application of 29 Si Solid-State NMR in Quantitative Analysis of Cement-Based Materials

XIAO Jian-min;LI Hui;DANG Yuan;XU Ming-lin   

  • Online:2017-12-15 Published:2021-01-18

摘要: 29 Si固体核磁共振技术是目前研究水泥基材料定量分析的有效工具之一,在水泥化学领域应用广泛.从现代分析测试技术入手,突出了29 Si固体核磁共振技术在水泥化学中的优势,并结合29 Si固体核磁共振定量分析技术和数据,从硅酸盐水泥熟料矿物组分、硅酸盐水泥水化过程量化表征及硅灰掺入的其他水泥基材料的定量分析等方面综述了29 Si固体核磁共振技术在水泥基材料定量分析中的应用,总结了29 Si固体核磁共振技术在水泥基材料领域定量分析存在的问题并展望了核磁共振技术在水泥基材料领域的发展趋势.

关键词: 水泥基材料;29SiNMR;定量分析;分峰拟合

Abstract: 29 Si solid-state Nuclear Magnetic Resonance ( NMR) technique is one of the effective tools in researching for quantitative analysis of cement-based materials , which is widely used in cement chemistry .In order to highlight the advantages of 29 Si NMR in cement chemistry , this article started with the modern analytical and testing techniques , and then combined quantitative analysis technics and data of 29 Si NMR.More importantly , this paper reviewed the application of 29 Si NMR in quantitative analysis of mineral composition of Portland cement clinker , cement hydration process and quantitative characterization of cement-based materials such as gypsum admixing silica fume .The problem of 29 Si NMR technique applied in cement quantitative analysis was proposed and the development of 29 Si NMR in cement-based materials was evaluated objectively .

Key words: cement-based material;29 Si NMR;quantitative analysis;peak fitting

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