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硅酸盐通报 ›› 2017, Vol. 36 ›› Issue (12): 3978-3983.

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缓凝剂改性磷建筑石膏及其机理研究

马保国;孙仲达;苏英;金子豪;祝路   

  1. 武汉理工大学硅酸盐建筑材料国家重点实验室,武汉,430070;湖北工业大学,武汉,430068
  • 出版日期:2017-12-15 发布日期:2021-01-18
  • 基金资助:
    十三五国家重点研发计划子课题(2016YFC0700904-01)%湖北省重大科技创新计划项目(2014ACC015)

Mechanism Research of Phosphor Building Gypsum with Retarder Modified

MA Bao-guo;SUN Zhong-da;SU Ying;JIN Zi-hao;ZHU Lu   

  • Online:2017-12-15 Published:2021-01-18

摘要: 研究了不同种类缓凝剂对磷建筑石膏凝结时间和力学强度的影响,测试了添加不同种类缓凝剂后磷建筑石膏的绝干密度,水化热.并利用XRD检测了磷建筑石膏的物相组成,运用SEM分析了改性后磷建筑石膏的微观形貌.结果表明:NS、NP和SC对磷建筑石膏均具有一定的缓凝作用,但效果不同,SC缓凝效果优于其他两种;在相同掺量的情况下,SC对磷建筑石膏硬化体强度影响较为明显,并且其对磷建筑石膏硬化体绝干密度的影响也最大.缓凝剂SC可以使磷建筑石膏的水化放热时间推迟,降低了水化放热峰.缓凝剂SC的合适掺量范围为0.1%~0.2%.实验结果为进一步研究磷建筑石膏的缓凝机理提供了参考价值.

关键词: 磷建筑石膏;缓凝剂;水化热;力学性能

Abstract: In this experiment , we have researched the effects of different types of retarders on phosphor building gypsum setting time and mechanical strength , and text the dry density and hydration heat of phosphor building gypsum after added different types of retarders .The phase composition of the plaster was studied by XRD , and the microstructure of modified plaster was studied by SEM .The research finding shows that NS , NP and SC have a certain retardation effect on phosphorus building gypsum , but the effect is different , the best effect of retardation is SC;In the case of the same amount of content , the maximum effect on the strength of the hardened body of the gypsum is SC , and its effect on the dry density of hardened body in phosphorus building gypsum is also the greatest .SC can make the hydration heat of the phosphorus building gypsum delayed , and reducing the hydration exothermic peak .The suitable dosage range of SC is 0.1%-0.2%.The experimental results provide a reference value for the further study of the retardation mechanism of phosphorus building gypsum .

Key words: phosphor building gypsum;retarder;hydration heat;mechanical property

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