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硅酸盐通报 ›› 2017, Vol. 36 ›› Issue (9): 2951-2957.

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热处理对Sb:SnO2透明导电薄膜光电性能的影响

梁斐;赵修建;倪佳苗;郑敏栋   

  1. 武汉理工大学硅酸盐建筑材料国家重点实验室,武汉,430070;武汉理工大学硅酸盐建筑材料国家重点实验室,武汉 430070;湖北第二师范学院建筑与材料工程学院,武汉 430205
  • 出版日期:2017-09-15 发布日期:2021-01-18
  • 基金资助:
    湖北省技术创新重大项目(2013AAA005)%湖北省自然科学基金面上项目(2014CFB563)

Effect of Heat Treatment on the Optical and Electrical Properties of Sb:SnO2 Transparent Conduction Films

LIANG Fei;ZHAO Xiu-jian;NI Jia-miao;ZHENG Min-dong   

  • Online:2017-09-15 Published:2021-01-18

摘要: 由烧结法制备了5Sb2O5·95SnO2(mol%)陶瓷靶材,以所制靶材利用射频磁控溅射法在石英玻璃基片上制备得到高质量的Sb:SnO2(ATO)透明导电薄膜,研究了热处理温度对ATO薄膜的结构和光学与电学性能的影响.结果表明:热处理对ATO薄膜的相结构,结晶质量及性能均有一定的影响.随着温度升高,所制薄膜的晶粒尺寸逐渐长大,方块电阻逐步减小,最小值为9.3Ω/□;红外反射率先增大后减小,并在热处理温度为600℃时达到极大值,为89%.薄膜可见光透过率均在80%以上,温度为600℃时最高达到91.3%.

关键词: Sb:SnO2;磁控溅射;红外反射;热处理

Abstract: The high quality Sb:SnO2 transparent conduction films were deposited on quartz glass by radio frequency magnetron sputtering using the 5Sb2O5· 95SnO2(mol%) ceramic target.The effects of heat treatment temperature on the structure , optical and electrical properties of ATO films were studied .The results show that all the phase structure , crystallinity and properties of ATO films are affected by heat treatment .The grain size of films increases with the increase of the heat treatment temperature , while the sheet resistance decreases until to its'minimum of 9 .3 Ω/□.The infrared reflectivity firstly increases and then decreases with increasing temperature and shows its'maximum ( about 89%) at 600 ℃.The transmittances of films are more than 80%in the visible region and the best sample treated at 600 ℃is up to 91 .3%.

Key words: Sb:SnO2;magnetron sputtering;infrared reflection;heat treatment

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