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硅酸盐通报 ›› 2017, Vol. 36 ›› Issue (7): 2392-2396.

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碱式硫酸镁水泥混凝土在硫酸盐溶液中的损伤过程研究

陈文海;吴成友;蒋宁山;张慧芳;郑树海;陈方宇   

  1. 青海大学土木工程学院,西宁,810016;中国科学院青海盐湖研究所,西宁,810008
  • 出版日期:2017-07-15 发布日期:2021-01-18
  • 基金资助:
    国家自然科学基金(U1407104,21401209,51662035)%教育部春晖计划项目(Z2015041)%青海省自然科学基金项目(2015-ZJ-937Q,2015-ZJ-722,2015-ZJ-947Q)%青海省高等学校地基与基础教研创新团队项目

Damage Process of Basic Magnesium Sulfate Cement Concrete in Sulfate Solution

CHEN Wen-hai;WU Cheng-you;JIANG Ning-shan;ZHANG Hui-fang;ZHENG Shu-hai;CHEN Fang-yu   

  • Online:2017-07-15 Published:2021-01-18

摘要: 采用干湿循环的试验方法研究碱式硫酸镁水泥(BMSC)混凝土抗硫酸盐腐蚀性能.以质量变化和相对动弹模量作为评价指标,研究了不掺加矿物掺合料(BMSC)、掺加30%粉煤灰(BMSC-F)碱式硫酸镁水泥和普通硅酸盐水泥(POC)混凝土抗硫酸盐腐蚀性能.结果表明:干湿循环前期,混凝土的质量缓慢增加;后期,混凝土的质量损失比较明显.在干湿循环的环境下,BMSC混凝土的Erd变化包括以下4阶段:上升段,缓慢下降段,线性上升段,加速下降段;POC混凝土的Erd随着干湿循环次数的增加,呈现先升高后下降的趋势.同等条件下,BMSC混凝土的抗硫酸盐腐蚀性能优于POC混凝土;掺加粉煤灰有利于提高BMSC混凝土的抗硫酸盐腐蚀能力.

关键词: 碱式硫酸镁水泥混凝土;干湿循环;抗硫酸盐腐蚀

Abstract: The sulfate corrosion resistance of basic magnesium sulfate cement(BMSC)concrete was investigated by dry-wet cycles.The influence of damage degree on the sulfate resistance of concrete was analyzed via the rate of mass loss and relative dynamic elastic modulus.The sulfate corrosion resistance of that without mineral admixtures(BMSC),with 30%fly ash(BMSC-F)basic magnesium sulfate cement and ordinary Portland cement(POC)concrete was studied.The result indicates that the quality of concrete increases slowly at the early period of the dry-wet cycles and the quality of the concrete damages obviously later.When under dry-wet cycling conditions,the relative dynamic module of elasticity of the BMSC concrete Erd exhibits a increasing stage followed by a slow decreasing stage,then a linear increasing stage,and finally the failure stage.The relative dynamic module of elasticity of the POC concrete Erd increases first and then decreases with the times of dry-wet cycles increasing.And under the same conditions,the sulfate corrosion resistance of BMSC concrete is better than that of POC concrete.And adding fly ash can improve the sulfate corrosion resistance of BMSC concrete.

Key words: basic magnesium sulfate cement concrete;dry-wet cycles;sulfate corrosion resistance

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