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硅酸盐通报 ›› 2017, Vol. 36 ›› Issue (1): 1-7.

• •    下一篇

不同掺量非晶态C12 A7/CaSO4·2 H2 O体系对OPC早期性能的影响及作用机理

张江涛;王栋民;王奕仁;李文平   

  1. 中国矿业大学 北京 化学与环境工程学院,混凝土与环境材料研究所,北京 100083
  • 出版日期:2017-01-15 发布日期:2021-01-18
  • 基金资助:
    国家自然科学基金(51572293)

Effects of Different Content of Amorphous C12 A7/CaSO4 ·2H2 O System on Early Properties of OPC and Mechanical Performance

ZHANG Jiang-tao;WANG Dong-min;WANG Yi-ren;LI Wen-ping   

  • Online:2017-01-15 Published:2021-01-18

摘要: 研究了不同掺量非晶态C12 A7/CaSO4·2H2 O体系对OPC净浆凝结时间、流动性和早期抗压强度的影响,通过XRD和SEM对水化产物的物相和形貌进行了表征,并采用量热试验对其水化历程进行了分析。结果表明:非晶态C12 A7/CaSO4·2H2 O体系掺量为5%,非晶态C12 A7与CaSO4·2H2 O的质量比为1.0∶1.0时,非晶态C12 A7/CaSO4·2H2 O体系能够促进C3 S和C2 S的水化,生成C-S-H凝胶相互交织搭接形成网络结构而促进凝结;同时也促使OPC水化早期产生大量针状晶体钙矾石,钙矾石与前期生成的C-S-H凝胶相互填充,使水化产物结构密实,提高早期强度。

关键词: 非晶态C12 A7;钙矾石;早期抗压强度;水化

Abstract: The effect of different content of amorphous C12 A7/CaSO4 · 2H2 O system on the early properties of setting time, fluidity and compressive strength of OPC was to investigate. Hydration products were tested by X-ray diffraction ( XRD ) and Scanning electron microscope ( SEM ) , and hydration process was analyzed by calorimetric method. The results show that C12 A7/CaSO4 ·2H2 O system used 5% of unit weight of cement, the mass ratio of C12 A7 and CaSO4 ·2H2 O was 1. 0 to 1. 0, the system accelerated the hydration of C3 S and C2 S, the hydration product C-S-H gel intertwined overlap to form the network structure which resulted the quick setting of cement paste, it also formed a large amount of acicular ettringite, the structure of hydration products was more and more compact, because of the ettringite filled with C-S-H gel each other, it improved the early strength of cement paste.

Key words: amorphous C12 A7;ettringite;early compressive strength;hydration

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