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硅酸盐通报 ›› 2016, Vol. 35 ›› Issue (9): 3072-3076.

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废弃石英坩埚资源化制备方石英质瓷

孙健;李家科;王艳香;朱海翔   

  1. 景德镇陶瓷大学材料科学与工程学院,景德镇,333001
  • 出版日期:2016-09-15 发布日期:2021-01-18
  • 基金资助:
    江西省社会发展计划项目资助(20122BBG70070)

Preparation of Cristobalite-based Ceramics Using the Discarded Quartz Crucible

SUN Jian;LI Jia-ke;WANG Yan-xiang;ZHU Hai-xiang   

  • Online:2016-09-15 Published:2021-01-18

摘要: 以废弃石英坩埚、苏州土、长石和铝矾土等为原料制备方石英质瓷。采用XRD、SEM、热膨胀仪和材料试验机等测试方法,研究了配方组成和烧成温度对方石英质瓷的物相组成、微观形貌和机械性能影响规律。结果表明:当配料配方中废弃石英坩埚40%、苏州土40%、钾长石15%和铝矾土5%,在烧成温度1300℃、保温时间30 min条件下,可以获得机械性能较佳的方石英质瓷,其弯曲强度为76.45 MPa,热稳定性△T ≥180℃,热膨胀系数为7.16×10-6℃-1( RT~600℃)。

关键词: 废弃石英坩埚;方石英质瓷;制备工艺;性能

Abstract: Cristobalite-based ceramics were prepared using the discarded quartz crucible , kaolin, feldspar and bauxite as raw materials .The effects of batch formula and firing temperature on phase composition , microstructure , coefficient of thermal expansion and mechanical performances of cristobalite-based ceramics were investigated by XRD , SEM, thermal dilatometer and material testing machine .The results show that cristobalite-based ceramics with good mechanical performances are obtained when discarded quartz crucible 40%, kaolin 40%, feldspar 15% and bauxite 5% at 1300 ℃ for 30 min .Bending strength and coefficient of thermal expansion of cristobalite-based ceramic are 76.45 MPa and 7.16 × 10 -6℃-1 ( RT~600 ℃) ,respectively .And thermal shock resistance (△T ) is above 180 ℃.

Key words: discarded quartz crucible;cristobalite-based ceramic;preparation technique;performance

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