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硅酸盐通报 ›› 2016, Vol. 35 ›› Issue (9): 2753-2758.

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K +和 Na +在 C3 S-纳米 SiO2浆体上的吸附和脱附特性

钱海龙;邓敏;陈碧;王志磊;陆国森   

  1. 国家“江苏先进生物与化学制造协同创新中心”,南京,210009;国家“江苏先进生物与化学制造协同创新中心”,南京 210009; 南京工业大学材料科学与工程学院,材料化学工程国家重点实验室,南京 210009
  • 出版日期:2016-09-15 发布日期:2021-01-18
  • 基金资助:
    教育部长江学者和创新团队发展计划(PCSIRT,IRT1146);江苏省普通高校研究生科研创新计划项目(KYLX15_0781)

Adsorption and Desorption Characteristics of K+and Na+on C3 S-nano-SiO2 Pastes

QIAN Hai-long;DENG Min;CHEN Bi;WANG Zhi-lei;LU Guo-sen   

  • Online:2016-09-15 Published:2021-01-18

摘要: 采用分析纯试剂合成的C3 S和纳米SiO2水化制备浆体,利用ζ-电位仪、X-射线衍射仪和N2-吸附脱附表征浆体的电性能、物相组成和比表面积,研究了用去离子水拌合的浆体对K+和Na+的吸附与脱附性能和用碱溶液拌合的浆体持留K+和Na+的能力。结果表明:在碱溶液中,采用去离子水拌合的C3 S-纳米SiO2浆体粉末吸附K+和Na+的量随碱溶液浓度的升高而增大;采用碱溶液拌合的浆体粉末经去离子水充分洗涤后,浆体中仍残留部分K+和Na+。纳米SiO2掺量越大,浆体对K+和Na+的吸附能力越大。采用去离子水拌合的C3 S-纳米SiO2浆体粉末对K+和Na+的吸附主要是物理吸附。浆体对K+和Na+的吸附无明显选择性。

关键词: C3 S-纳米SiO2 浆体;吸附;脱附;K+;Na+

Abstract: C3 S synthesized with analytically pure compounds and nano-SiO2 were used to prepare pastes . The electrical properties , phase composition and specific surface area of the pastes were characterized by means of ζpotential measurement , X-ray diffraction and adsorption-desorption of N 2 , respectively .The adsorption and desorption properties of K +and Na +by the pastes mixed with de-ionized water or alkali solutions were investigated .The results show that the higher the replacement level of nano-SiO2 , the larger the ability of C 3 S-nano-SiO2 pastes to bind alkali .There is no obvious difference between amount of K+and Na +adsorbed by the pastes .Adsorption of K +and Na +by the pastes mixed with de-ionized water is mainly with physical adsorption .There are few residual alkali ions in the pastes mixed with alkali solutions after washed with enough de-ionized water .

Key words: C3 S-nano-SiO2 paste;adsorption;desorption;K+;Na+

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